The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries
Abstract
High-voltage (>4.3 V) rechargeable lithium (Li) metal batteries (LMBs) face huge obstacles due to the high reactivity of Li metal with traditional electrolytes. Despite their good stability with Li metal, conventional ether-based electrolytes are typically used only in <4.0 V LMBs because of their limited oxidation stability. Here we report high-concentration ether electrolytes that can induce the formation of a unique cathode electrolyte interphase via the synergy between the salt and the ether solvent, which effectively stabilizes the catalytically active cathodes and preserves their structural integrity under high voltages. Eventually, LMBs can retain 92% capacity after 500 cycles at 4.3 V with very limited Li consumption. More importantly, such ether electrolytes enable stable battery cycling not only under voltages as high as 4.5 V but also on highly demanding Ni-rich layered cathodes. These findings significantly expand knowledge of ether electrolytes and provide new perspectives of electrolyte design for high-energy-density LMBs.
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Cites
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
Xu, K. (2004) · Chemical Reviews · doi:10.1021/cr030203g · Cited by 7,437
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Lithium metal anodes for rechargeable batteries
Xu, W., Wang, J., Ding, F., Chen, X., Nasybulin, E., Zhang, Y., & Zhang, J.-G. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee40795k · Cited by 4,704
Self-citationHigh rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Self-citationNickel‐Rich Layered Lithium Transition‐Metal Oxide for High‐Energy Lithium‐Ion Batteries
Liu, W., Oh, P., Liu, X., Lee, M., Cho, W., Chae, S., Kim, Y., & Cho, J. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409262 · Cited by 1,960
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Ryu, H.-H., Park, K.-J., Yoon, C. S., & Sun, Y.-K. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b05269 · Cited by 1,629
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
Li, W., Yao, H., Yan, K., Zheng, G., Liang, Z., Chiang, Y.-M., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8436 · Cited by 1,540
Myung, S.-T., Maglia, F., Park, K.-J., Yoon, C. S., Lamp, P., Kim, S.-J., & Sun, Y.-K. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00594 · Cited by 1,382
Cited by
Lithium Metal Anodes with Nonaqueous Electrolytes
Zhang, J.-G., Xu, W., Xiao, J., Cao, X., & Liu, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00275 · Cited by 730
Self-citationCritical effects of electrolyte recipes for Li and Na metal batteries
Zheng, X., Huang, L., Ye, X., Zhang, J., Min, F., Luo, W., & Huang, Y. (2021) · Chem · doi:10.1016/j.chempr.2021.02.025 · Cited by 367
Self-citationHoloubek, J., Yu, M., Yu, S., Li, M., Wu, Z., Xia, D., Bhaladhare, P., Gonzalez, M. S., Pascal, T. A., Liu, P., et al. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00643 · Cited by 351
Cao, Z., Zheng, X., Qu, Q., Huang, Y., & Zheng, H. (2021) · Advanced Materials · doi:10.1002/adma.202103178 · Cited by 336
Li, Z., Rao, H., Atwi, R., Sivakumar, B. M., Gwalani, B., Gray, S., Han, K. S., Everett, T. A., Ajantiwalay, T. A., Murugesan, V., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-36647-1 · Cited by 292
Metadata
- Authors
- Ren, X., Zou, L., Jiao, S., Mei, D., Engelhard, M. H., Li, Q., Lee, H., Niu, C., Adams, B. D., Wang, C., Liu, J., Zhang, J.-G., & Xu, W.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-03-20
- Volume
- 4
- Issue
- 4
- Pages
- 896-902
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2924964892
- Cited by
- 502
- References
- 36
- FWCI
- 17.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ren, X., Zou, L., Jiao, S., Mei, D., Engelhard, M. H., Li, Q., Lee, H., Niu, C., Adams, B. D., Wang, C., Liu, J., Zhang, J.-G., & Xu, W. (2019). High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.9b00381
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