The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Visualizing Chemomechanical Degradation of a Solid-State Battery Electrolyte
Abstract
Transformations at interfaces between solid-state electrolytes (SSEs) and lithium metal electrodes can lead to high impedance and capacity decay during cycling of solid-state batteries, but the links between structural/chemical/mechanical evolution of interfaces and electrochemistry are not well understood. Here, we use in situ X-ray computed tomography to reveal the evolution of mechanical damage within a Li 1+ x Al x Ge 2– x (PO 4 ) 3 (LAGP) SSE caused by interphase growth during electrochemical cycling. The growth of an interphase with expanded volume drives fracture in this material, and the extent of fracture during cycling is found to be the primary factor causing the impedance increase, as opposed to the resistance of the interphase itself. Cracks are observed to initiate near the edge of the lithium/LAGP interface, which agrees with simulations. The chemomechanical effects of interphase growth studied here are expected to play a role in a variety of SSE materials, and this work is a step toward designing durable interfaces.
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Cites
Challenges in the development of advanced Li-ion batteries: a review
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Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes
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Cited by
Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries
Krauskopf, T., Richter, F. H., Zeier, W. G., & Janek, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00431 · Cited by 892
Solid-state lithium batteries: Safety and prospects
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Lewis, J. A., Cortes, F. J. Q., Liu, Y., Miers, J. C., Verma, A., Vishnugopi, B. S., Tippens, J., Prakash, D., Marchese, T. S., Han, S. Y., et al. (2021) · Nature Materials · doi:10.1038/s41563-020-00903-2 · Cited by 444
Self-citationSulfide and Oxide Inorganic Solid Electrolytes for All-Solid-State Li Batteries: A Review
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Electrolyte/Electrode Interfaces in All-Solid-State Lithium Batteries: A Review
Pang, Y., Pan, J., Yang, J., Zheng, S., & Wang, C. (2021) · Electrochemical Energy Reviews · doi:10.1007/s41918-020-00092-1 · Cited by 313
Metadata
- Authors
- Tippens, J., Miers, J. C., Afshar, A., Lewis, J. A., Cortes, F. J. Q., Qiao, H., Marchese, T. S., Di Leo, C. V., Saldana, C., & McDowell, M. T.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-06-04
- Volume
- 4
- Issue
- 6
- Pages
- 1475-1483
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2948700419
- Cited by
- 309
- References
- 41
- FWCI
- 13.31
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tippens, J., Miers, J. C., Afshar, A., Lewis, J. A., Cortes, F. J. Q., Qiao, H., Marchese, T. S., Di Leo, C. V., Saldana, C., & McDowell, M. T. (2019). Visualizing Chemomechanical Degradation of a Solid-State Battery Electrolyte. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.9b00816
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