The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.
New Insight on the Role of Electrolyte Additives in Rechargeable Lithium Ion Batteries
Abstract
Solid electrolyte interphase (SEI)-forming agents such as vinylene carbonate, sulfone, and cyclic sulfate are commonly believed to be film-forming additives in lithium-ion batteries that help to enhance graphite anode stability. However, we find that the film-forming effect and the resultant SEI may not be the only reasons for the enhanced graphite stability. This is because the as-formed SEI cannot inhibit Li + –solvent co-intercalation once the additive is removed from the electrolyte. Instead, we show that the Li + solvation structure, which is modified by these additives, plays a critical role in achieving reversible Li + (de)intercalation within graphite. This discovery is confirmed in both carbonate and ether-based electrolytes. We show that the problem of graphite exfoliation caused by Li + –solvent co-intercalation can be mitigated by adding ethene sulfate to tune the Li + coordination structure. This work brings new insight into the role of additives in electrolytes, expanding the prevailing thinking over the past 2 decades. In addition, this finding can guide the design of more versatile electrolytes for advanced rechargeable metal-ion batteries.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Issues and challenges facing rechargeable lithium batteries
Tarascon, J.-M., & Armand, M. (2001) · Nature · doi:10.1038/35104644 · Cited by 21,130
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
Xu, K. (2004) · Chemical Reviews · doi:10.1021/cr030203g · Cited by 7,437
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
Verma, P., Maire, P., & Novák, P. (2010) · Electrochimica Acta · doi:10.1016/j.electacta.2010.05.072 · Cited by 2,903
Cation-π Interactions in Chemistry and Biology: A New View of Benzene, Phe, Tyr, and Trp
Dougherty, D. A. (1996) · Science · doi:10.1126/science.271.5246.163 · Cited by 2,656
A review on electrolyte additives for lithium-ion batteries
Zhang, S. S. (2006) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.07.074 · Cited by 1,831
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
Li, W., Yao, H., Yan, K., Zheng, G., Liang, Z., Chiang, Y.-M., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8436 · Cited by 1,540
Yamada, Y., Furukawa, K., Sodeyama, K., Kikuchi, K., Yaegashi, M., Tateyama, Y., & Yamada, A. (2014) · Journal of the American Chemical Society · doi:10.1021/ja412807w · Cited by 1,525
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
Zheng, J., Engelhard, M. H., Mei, D., Jiao, S., Polzin, B. J., Zhang, J.-G., & Xu, W. (2017) · Nature Energy · doi:10.1038/nenergy.2017.12 · Cited by 1,343
Cited by
Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries
Cheng, H., Sun, Q., Li, L., Zou, Y., Wang, Y., Cai, T., Zhao, F., Liu, G., Ma, Z., Wahyudi, W., et al. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02425 · Cited by 640
Self-citationElectrochemical energy storage devices working in extreme conditions
Chen, M., Zhang, Y., Xing, G., Chou, S.-L., & Tang, Y. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00271f · Cited by 346
Research Progresses of Liquid Electrolytes in Lithium‐Ion Batteries
Liu, Y., Zhao, C., Du, J., Zhang, X., Chen, A., & Zhang, Q. (2023) · Small · doi:10.1002/smll.202205315 · Cited by 328
Challenges and development of lithium-ion batteries for low temperature environments
Piao, N., Gao, X., Yang, H., Guo, Z., Hu, G., Cheng, H.-M., & Li, F. (2022) · eTransportation · doi:10.1016/j.etran.2021.100145 · Cited by 324
Low‐Temperature Electrolyte Design for Lithium‐Ion Batteries: Prospect and Challenges
Li, Q., Liu, G., Cheng, H., Sun, Q., Zhang, J., & Ming, J. (2021) · Chemistry – A European Journal · doi:10.1002/chem.202101407 · Cited by 268
Self-citation
Metadata
- Authors
- Ming, J., Cao, Z., Wu, Y., Wahyudi, W., Wang, W., Guo, X., Cavallo, L., Hwang, J.-Y., Shamim, A., Li, L.-J., Sun, Y.-K., & Alshareef, H. N.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-10-08
- Volume
- 4
- Issue
- 11
- Pages
- 2613-2622
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2979895419
- Cited by
- 294
- References
- 58
- FWCI
- 9.43
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: New Insight on the Role of Electrolyte Additives in Rechargeable Lithium Ion Batteries. https://app.cochat.ai/papers/10.1021/acsenergylett.9b01441
- The paper
- Ming, J., Cao, Z., Wu, Y., Wahyudi, W., Wang, W., Guo, X., Cavallo, L., Hwang, J.-Y., Shamim, A., Li, L.-J., Sun, Y.-K., & Alshareef, H. N. (2019). New Insight on the Role of Electrolyte Additives in Rechargeable Lithium Ion Batteries. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.9b01441
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
