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Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization
Open accessAbstract
In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition-fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface functionality. Given its potential scalability, such environmentally-friendly formulations are expected to offer many potential applications, such as novel Pickering emulsifiers, efficient microencapsulation vehicles, and sterilizable thermo-responsive hydrogels for the cost-effective long-term storage of mammalian cells.
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Cites
Matrix elasticity directs stem cell lineage specification
Engler, A. J., Sen, S., Sweeney, H. L., & Discher, D. E. (2006) · Cell · doi:10.1016/j.cell.2006.06.044 · Cited by 13,915
Blanazs, A., Armes, S. P., & Ryan, A. J. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800713 · Cited by 1,500
Self-citationSZWARC, M. (1956) · Nature · doi:10.1038/1781168a0 · Cited by 1,360
On the origins of morphological complexity in block copolymer surfactants
Jain, S., & Bates, F. S. (2003) · Science · doi:10.1126/science.1082193 · Cited by 1,217
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Cited by
Rieger, J. (2015) · Macromolecular Rapid Communications · doi:10.1002/marc.201500028 · Cited by 349
Pesenti, T., & Nicolas, J. (2020) · ACS Macro Letters · doi:10.1021/acsmacrolett.0c00676 · Cited by 214
Cheng, C.-C., Huang, J.-J., Lee, A.-W., Huang, S.-Y., Huang, C.-Y., & Lai, J.-Y. (2019) · ACS Applied Bio Materials · doi:10.1021/acsabm.9b00146 · Cited by 25
A biomimetic magnetosome: Formation of iron oxide within carboxylic acid terminated polymersomes
Bain, J., Legge, C. J., Beattie, D. L., Sahota, A., Dirks, C., Lovett, J. R., & Staniland, S. S. (2019) · Nanoscale · doi:10.1039/c9nr00498j · Cited by 21
Fonseca Parra, E. P., Oumerri, J., Arteni, A. A., Six, J.-L., Armes, S. P., & Ferji, K. (2025) · Macromolecules · doi:10.1021/acs.macromol.4c01772 · Cited by 8
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Metadata
- Authors
- Warren, N. J., & Armes, S. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-15
- Volume
- 136
- Issue
- 29
- Pages
- 10174-10185
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1970571815
- Cited by
- 1,107
- References
- 5
- FWCI
- 42.35
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Warren, N. J., & Armes, S. P. (2014). Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization. Journal of the American Chemical Society. https://doi.org/10.1021/ja502843f
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