The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Emerging Trends in Polymerization-Induced Self-Assembly
Open accessAbstract
In this Perspective, we summarize recent progress in polymerization-induced self-assembly (PISA) for the rational synthesis of block copolymer nanoparticles with various morphologies. Much of the PISA literature has been based on thermally initiated reversible addition-fragmentation chain transfer (RAFT) polymerization. Herein, we pay particular attention to alternative PISA protocols, which allow the preparation of nanoparticles with improved control over copolymer morphology and functionality. For example, initiation based on visible light, redox chemistry, or enzymes enables the incorporation of sensitive monomers and fragile biomolecules into block copolymer nanoparticles. Furthermore, PISA syntheses and postfunctionalization of the resulting nanoparticles (e.g., cross-linking) can be conducted sequentially without intermediate purification by using various external stimuli. Finally, PISA formulations have been optimized via high-throughput polymerization and recently evaluated within flow reactors for facile scale-up syntheses.
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Cites
The Hitchhiker’s Guide to Flow Chemistry
Plutschack, M. B., Pieber, B., Gilmore, K., & Seeberger, P. H. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00183 · Cited by 1,995
Therapeutic Protein–Polymer Conjugates: Advancing Beyond PEGylation
Pelegri-O’Day, E. M., Lin, E.-W., & Maynard, H. D. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504390x · Cited by 622
Cited by
Polymerization techniques in polymerization-induced self-assembly (PISA)
Liu, C., Hong, C.-Y., & Pan, C.-Y. (2020) · Polymer Chemistry · doi:10.1039/d0py00455c · Cited by 282
Beygi, M., Oroojalian, F., Hosseini, S. S., Mokhtarzadeh, A., Kesharwani, P., & Sahebkar, A. (2023) · Progress in Materials Science · doi:10.1016/j.pmatsci.2023.101209 · Cited by 32
RetractedFonseca Parra, E. P., Oumerri, J., Arteni, A. A., Six, J.-L., Armes, S. P., & Ferji, K. (2025) · Macromolecules · doi:10.1021/acs.macromol.4c01772 · Cited by 8
Self-citationChittari, S. S., Dykeman-Bermingham, P. A., Elder, B. M., & Knight, A. S. (2025) · Macromolecules · doi:10.1021/acs.macromol.5c02363 · Cited by 6
Metadata
- Authors
- Penfold, N. J. W., Yeow, J., Boyer, C., & Armes, S. P.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-08-07
- Volume
- 8
- Issue
- 8
- Pages
- 1029-1054
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2965497785
- Cited by
- 647
- References
- 2
- FWCI
- 29.96
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Penfold, N. J. W., Yeow, J., Boyer, C., & Armes, S. P. (2019). Emerging Trends in Polymerization-Induced Self-Assembly. ACS Macro Letters. https://doi.org/10.1021/acsmacrolett.9b00464
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