The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti 3 C 2 MXene
Open accessAbstract
One of the primary factors limiting further research and commercial use of the two-dimensional (2D) titanium carbide MXene Ti 3 C 2, as well as MXenes in general, is the rate at which freshly made samples oxidize and degrade when stored as aqueous suspensions. Here, we show that including excess aluminum during synthesis of the Ti 3 AlC 2 MAX phase precursor leads to Ti 3 AlC 2 grains with improved crystallinity and carbon stoichiometry (termed Al–Ti 3 AlC 2 ). MXene nanosheets (Al–Ti 3 C 2 ) produced from this precursor are of higher quality, as evidenced by their increased resistance to oxidation and an increase in their electronic conductivity up to 20 000 S/cm. Aqueous suspensions of stoichiometric single- to few-layer Al–Ti 3 C 2 flakes produced from the modified Al–Ti 3 AlC 2 have a shelf life of over ten months, compared to 1 to 2 weeks for previously published Ti 3 C 2, even when stored in ambient conditions. Freestanding films made from Al–Ti 3 C 2 suspensions stored for ten months show minimal decreases in electrical conductivity and negligible oxidation. Furthermore, oxidation of the improved Al–Ti 3 C 2 in air initiates at temperatures that are 100–150 °C higher than that of conventional Ti 3 C 2 . The observed improvements in both the shelf life and properties of Al–Ti 3 C 2 will facilitate the widespread use of this material.
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Cites
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
Jain, A., Ong, S. P., Hautier, G., Chen, W., Richards, W. D., Dacek, S., Cholia, S., Gunter, D., Skinner, D., Ceder, G., et al. (2013) · APL Materials · doi:10.1063/1.4812323 · Cited by 13,094
Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2T x MXene
Sarycheva, A., & Gogotsi, Y. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c00359 · Cited by 1,467
Self-citation
Cited by
The world of two-dimensional carbides and nitrides (MXenes)
VahidMohammadi, A., Rosen, J., & Gogotsi, Y. (2021) · Science · doi:10.1126/science.abf1581 · Cited by 3,191
Self-citationTen Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Self-citationRecent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
High-Entropy 2D Carbide MXenes: TiVNbMoC 3 and TiVCrMoC 3
Nemani, S. K., Zhang, B., Wyatt, B. C., Hood, Z. D., Manna, S., Khaledialidusti, R., Hong, W., Sternberg, M. G., Sankaranarayanan, S. K. R. S., & Anasori, B. (2021) · ACS Nano · doi:10.1021/acsnano.1c02775 · Cited by 423
Perspectives of 2D MXene Tribology
Rosenkranz, A., Righi, M. C., Sumant, A. V., Anasori, B., & Mochalin, V. N. (2023) · Advanced Materials · doi:10.1002/adma.202207757 · Cited by 331
Metadata
- Authors
- Mathis, T. S., Maleski, K., Goad, A., Sarycheva, A., Anayee, M., Foucher, A. C., Hantanasirisakul, K., Shuck, C. E., Stach, E. A., & Gogotsi, Y.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-04-13
- Volume
- 15
- Issue
- 4
- Pages
- 6420-6429
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W3156227411
- Cited by
- 1,001
- References
- 2
- FWCI
- 43.46
- Type
- journal article
- Language
- en
- Open access
- green
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- Mathis, T. S., Maleski, K., Goad, A., Sarycheva, A., Anayee, M., Foucher, A. C., Hantanasirisakul, K., Shuck, C. E., Stach, E. A., & Gogotsi, Y. (2021). Modified MAX Phase Synthesis for Environmentally Stable and Highly Conductive Ti 3 C 2 MXene. ACS Nano. https://doi.org/10.1021/acsnano.0c08357
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