The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)
Open accessAbstract
The higher the chemical diversity and structural complexity of two-dimensional (2D) materials, the higher the likelihood they possess unique and useful properties. Herein, density functional theory (DFT) is used to predict the existence of two new families of 2D ordered, carbides (MXenes), M'2M″C2 and M'2M″2C3, where M' and M″ are two different early transition metals. In these solids, M' layers sandwich M″ carbide layers. By synthesizing Mo2TiC2Tx, Mo2Ti2C3Tx, and Cr2TiC2Tx (where T is a surface termination), we validated the DFT predictions. Since the Mo and Cr atoms are on the outside, they control the 2D flakes' chemical and electrochemical properties. The latter was proven by showing quite different electrochemical behavior of Mo2TiC2Tx and Ti3C2Tx. This work further expands the family of 2D materials, offering additional choices of structures, chemistries, and ultimately useful properties.
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Cited by
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
Seh, Z. W., Fredrickson, K. D., Anasori, B., Kibsgaard, J., Strickler, A. L., Lukatskaya, M. R., Gogotsi, Y., Jaramillo, T. F., & Vojvodic, A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00247 · Cited by 1,482
Self-citationTen Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Self-citationRoom Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene)
Lee, E., VahidMohammadi, A., Prorok, B. C., Yoon, Y. S., Beidaghi, M., & Kim, D.-J. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b11055 · Cited by 878
Self-citationElectromagnetic absorption materials: Current progress and new frontiers
Lv, H., Yang, Z., Pan, H., & Wu, R. (2022) · Progress in Materials Science · doi:10.1016/j.pmatsci.2022.100946 · Cited by 837
Electrically-Transduced Chemical Sensors Based on Two-Dimensional Nanomaterials
Meng, Z., Stolz, R. M., Mendecki, L., & Mirica, K. A. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00311 · Cited by 773
Metadata
- Authors
- Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L., Kent, P. R. C., Gogotsi, Y., & Barsoum, M. W.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-13
- Volume
- 9
- Issue
- 10
- Pages
- 9507-9516
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1009208869
- Cited by
- 2,110
- References
- 45
- FWCI
- 33.31
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L., Kent, P. R. C., Gogotsi, Y., & Barsoum, M. W. (2015). Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes). ACS Nano. https://doi.org/10.1021/acsnano.5b03591
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