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Cited by 2,110

The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.

Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)

Open access
Anasori, Babak, Xie, Yu, Beidaghi, Majid, Lu, Jun, Hosler, Brian C., Hultman, Lars, Kent, Paul R. C., Gogotsi, Yury, Barsoum, Michel W.·2015·ACS Nano

Abstract

The higher the chemical diversity and structural complexity of two-dimensional (2D) materials, the higher the likelihood they possess unique and useful properties. Herein, density functional theory (DFT) is used to predict the existence of two new families of 2D ordered, carbides (MXenes), M'2M″C2 and M'2M″2C3, where M' and M″ are two different early transition metals. In these solids, M' layers sandwich M″ carbide layers. By synthesizing Mo2TiC2Tx, Mo2Ti2C3Tx, and Cr2TiC2Tx (where T is a surface termination), we validated the DFT predictions. Since the Mo and Cr atoms are on the outside, they control the 2D flakes' chemical and electrochemical properties. The latter was proven by showing quite different electrochemical behavior of Mo2TiC2Tx and Ti3C2Tx. This work further expands the family of 2D materials, offering additional choices of structures, chemistries, and ultimately useful properties.

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Metadata

Authors
Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L., Kent, P. R. C., Gogotsi, Y., & Barsoum, M. W.
Venue
ACS Nano
Published
2015-08-13
Volume
9
Issue
10
Pages
9507-9516
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W1009208869
Cited by
2,110
References
45
FWCI
33.31
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes). https://app.cochat.ai/papers/10.1021/acsnano.5b03591
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Anasori, B., Xie, Y., Beidaghi, M., Lu, J., Hosler, B. C., Hultman, L., Kent, P. R. C., Gogotsi, Y., & Barsoum, M. W. (2015). Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes). ACS Nano. https://doi.org/10.1021/acsnano.5b03591

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