Cited by 878Gas Sensing Nanomaterials and SensorsMXene and MAX Phase MaterialsAdvanced Sensor and Energy Harvesting Materials

Room Temperature Gas Sensing of Two-Dimensional Titanium Carbide (MXene)

Lee, Eunji, VahidMohammadi, Armin, Prorok, Barton C., Yoon, Young Soo, Beidaghi, Majid, Kim, Dong-Joo·2017·ACS Applied Materials & Interfaces

Abstract

Wearable gas sensors have received lots of attention for diagnostic and monitoring applications, and two-dimensional (2D) materials can provide a promising platform for fabricating gas sensors that can operate at room temperature. In the present study, the room temperature gas-sensing performance of Ti 3 C 2 T x nanosheets was investigated. 2D Ti 3 C 2 T x (MXene) sheets were synthesized by removal of Al atoms from Ti 3 AlC 2 (MAX phases) and were integrated on flexible polyimide platforms with a simple solution casting method. The Ti 3 C 2 T x sensors successfully measured ethanol, methanol, acetone, and ammonia gas at room temperature and showed a p-type sensing behavior. The fabricated sensors showed their highest and lowest response toward ammonia and acetone gas, respectively. The limit of detection of acetone gas was theoretically calculated to be about 9.27 ppm, presenting better performance compared to other 2D material-based sensors. The sensing mechanism was proposed in terms of the interactions between the majority charge carriers of Ti 3 C 2 T x and gas species.

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Crossref · 10.1021/acsami.7b11055

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Authors
Lee, E., VahidMohammadi, A., Prorok, B. C., Yoon, Y. S., Beidaghi, M., & Kim, D.-J.
Affiliations
  • Auburn University (US)
  • Gachon University (KR)
Corresponding author
  • Beidaghi, Majid
  • Kim, Dong-Joo
Venue
ACS Applied Materials & Interfaces
Published
2017-10-11
Volume
9
Issue
42
Pages
37184-37190
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2760568872
Cited by
878
References
1
Citations by year
2026: 69 · 2025: 138 · 2024: 144 · 2023: 144 · 2022: 134 · 2021: 106 · 2020: 75 · 2019: 51 · 2018: 17
FWCI
16.26
Type
journal article
Language
en
Open access
closed
Locations
  • ACS Applied Materials & Interfaces (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • Office of Experimental Program to Stimulate Competitive Research (GRSP R11)
  • Samuel Ginn College of Engineering
  • Agency for Defense Development (UD160050BD)
  • Korea Institute of Energy Technology Evaluation and Planning (20158520000210)
Topics
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Gas Sensing Nanomaterials and Sensors
  • Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
  • Physical Sciences › Engineering › Biomedical Engineering › Advanced Sensor and Energy Harvesting Materials
Keywords
MXene, Ti3C2Tx nanosheets, room-temperature gas sensing, wearable gas sensors, flexible polyimide substrate, MAX phases, acetone detection, ammonia detection, ethanol detection, methanol detection, detection limit, sensing mechanism, two-dimensional materials

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