The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes
Open accessAbstract
This work describes silicon nanoparticle-based lithium-ion battery negative electrodes where multiple nonactive electrode additives (usually carbon black and an inert polymer binder) are replaced with a single conductive binder, in this case, the conducting polymer PEDOT: PSS. While enabling the production of well-mixed slurry-cast electrodes with high silicon content (up to 95 wt %), this combination eliminates the well-known occurrence of capacity losses due to physical separation of the silicon and traditional inorganic conductive additives during repeated lithiation/delithiation processes. Using an in situ secondary doping treatment of the PEDOT: PSS with small quantities of formic acid, electrodes containing 80 wt % SiNPs can be prepared with electrical conductivity as high as 4.2 S/cm. Even at the relatively high areal loading of 1 mg/cm(2), this system demonstrated a first cycle lithiation capacity of 3685 mA·h/g (based on the SiNP mass) and a first cycle efficiency of ∼78%. After 100 repeated cycles at 1 A/g this electrode was still able to store an impressive 1950 mA·h/g normalized to Si mass (∼75% capacity retention), corresponding to 1542 mA·h/g when the capacity is normalized by the total electrode mass. At the maximum electrode thickness studied (∼1.5 mg/cm(2)), a high areal capacity of 3 mA·h/cm(2) was achieved. Importantly, these electrodes are based on commercially available components and are produced by the standard slurry coating methods required for large-scale electrode production. Hence, the results presented here are highly relevant for the realization of commercial LiB negative electrodes that surpass the performance of current graphite-based negative electrode systems.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
Coleman, J. N., Lotya, M., O’Neill, A., Bergin, S. D., King, P. J., Khan, U., Young, K., Gaucher, A., De, S., Smith, R. J., et al. (2011) · Science · doi:10.1126/science.1194975 · Cited by 7,242
Self-citationHigh-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Introduction to Percolation Theory
Stauffer, D., Aharony, A., & Redner, S. (1993) · Physics Today · doi:10.1063/1.2808877 · Cited by 6,666
Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage
Bonaccorso, F., Colombo, L., Yu, G., Stoller, M., Tozzini, V., Ferrari, A. C., Ruoff, R. S., & Pellegrini, V. (2015) · Science · doi:10.1126/science.1246501 · Cited by 3,454
Poly(3,4-ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future
Groenendaal, L., Jonas, F., Freitag, D., Pielartzik, H., & Reynolds, J. R. (2000) · Advanced Materials · doi:10.1002/(sici)1521-4095(200004)12:7<481::aid-adma481>3.0.co;2-c · Cited by 3,420
Thackeray, M. M., Wolverton, C., & Isaacs, E. D. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21892e · Cited by 2,515
A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes
Liu, N., Lu, Z., Zhao, J., McDowell, M. T., Lee, H.-W., Zhao, W., & Cui, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.6 · Cited by 2,491
Wu, H., Chan, G., Choi, J. W., Ryu, I., Yao, Y., McDowell, M. T., Lee, S. W., Jackson, A., Yang, Y., Hu, L., et al. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.35 · Cited by 2,478
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation
Liu, X. H., Zhong, L., Huang, S., Mao, S. X., Zhu, T., & Huang, J. Y. (2012) · ACS Nano · doi:10.1021/nn204476h · Cited by 2,376
Cited by
Silicon‐Based Anodes for Lithium‐Ion Batteries: From Fundamentals to Practical Applications
Feng, K., Li, M., Liu, W., Kashkooli, A. G., Xiao, X., Cai, M., & Chen, Z. (2018) · Small · doi:10.1002/smll.201702737 · Cited by 1,042
Chen, H., Ling, M., Hencz, L., Ling, H. Y., Li, G., Lin, Z., Liu, G., & Zhang, S. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00241 · Cited by 958
Designing polymers for advanced battery chemistries
Lopez, J., Mackanic, D. G., Cui, Y., & Bao, Z. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0103-6 · Cited by 894
Bresser, D., Buchholz, D., Moretti, A., Varzi, A., & Passerini, S. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00640g · Cited by 640
The emerging era of supramolecular polymeric binders in silicon anodes
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Metadata
- Authors
- Higgins, T. M., Park, S.-H., King, P. J., Zhang, C. (., McEvoy, N., Berner, N. C., Daly, D., Shmeliov, A., Khan, U., Duesberg, G., Nicolosi, V., & Coleman, J. N.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-08
- Volume
- 10
- Issue
- 3
- Pages
- 3702-3713
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2292819900
- Cited by
- 481
- References
- 47
- FWCI
- 32.02
- Type
- journal article
- Language
- en
- Open access
- green
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- Higgins, T. M., Park, S.-H., King, P. J., Zhang, C. (., McEvoy, N., Berner, N. C., Daly, D., Shmeliov, A., Khan, U., Duesberg, G., Nicolosi, V., & Coleman, J. N. (2016). A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes. ACS Nano. https://doi.org/10.1021/acsnano.6b00218
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