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Highly Tunable Colloidal Perovskite Nanoplatelets through Variable Cation, Metal, and Halide Composition
Open accessAbstract
Colloidal perovskite nanoplatelets are a promising class of semiconductor nanomaterials-exhibiting bright luminescence, tunable and spectrally narrow absorption and emission features, strongly confined excitonic states, and facile colloidal synthesis. Here, we demonstrate the high degree of spectral tunability achievable through variation of the cation, metal, and halide composition as well as nanoplatelet thickness. We synthesize nanoplatelets of the form L2[ABX3]n-1BX4, where L is an organic ligand (octylammonium, butylammonium), A is a monovalent metal or organic molecular cation (cesium, methylammonium, formamidinium), B is a divalent metal cation (lead, tin), X is a halide anion (chloride, bromide, iodide), and n-1 is the number of unit cells in thickness. We show that variation of n, B, and X leads to large changes in the absorption and emission energy, while variation of the A cation leads to only subtle changes but can significantly impact the nanoplatelet stability and photoluminescence quantum yield (with values over 20%). Furthermore, mixed halide nanoplatelets exhibit continuous spectral tunability over a 1.5 eV spectral range, from 2.2 to 3.7 eV. The nanoplatelets have relatively large lateral dimensions (100 nm to 1 μm), which promote self-assembly into stacked superlattice structures-the periodicity of which can be adjusted based on the nanoplatelet surface ligand length. These results demonstrate the versatility of colloidal perovskite nanoplatelets as a material platform, with tunability extending from the deep-UV, across the visible, into the near-IR. In particular, the tin-containing nanoplatelets represent a significant addition to the small but increasingly important family of lead- and cadmium-free colloidal semiconductors.
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The emergence of perovskite solar cells
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Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3
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Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
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2D Ruddlesden–Popper Perovskites for Optoelectronics
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Recent developments in emerging two-dimensional materials and their applications
Khan, K., Tareen, A. K., Aslam, M., Wang, R., Zhang, Y., Mahmood, A., Ouyang, Z., Zhang, H., & Guo, Z. (2020) · Journal of Materials Chemistry C · doi:10.1039/c9tc04187g · Cited by 886
Quantum and Dielectric Confinement Effects in Lower-Dimensional Hybrid Perovskite Semiconductors
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Metadata
- Authors
- Weidman, M. C., Seitz, M., Stranks, S. D., & Tisdale, W. A.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-08
- Volume
- 10
- Issue
- 8
- Pages
- 7830-7839
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2494207721
- Cited by
- 629
- References
- 57
- FWCI
- 31.71
- Type
- journal article
- Language
- en
- Open access
- hybrid
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