The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Phase Restructuring in Transition Metal Dichalcogenides for Highly Stable Energy Storage
Open accessAbstract
Abstract Achieving homogeneous phase transition and uniform charge distribution is essential for good cycle stability and high capacity when phase conversion materials are used as electrodes. Herein, we show that chemical lithiation of bulk 2H-MoS2 distorts its crystalline domains in three primary directions to produce mosaic-like 1T′ nanocrystalline domains, which improve phase and charge uniformity during subsequent electrochemical phase conversion. 1T′-LixMoS2, a macroscopic dense material with interconnected nanoscale grains, shows excellent cycle stability and rate capability in a lithium rechargeable battery compared to bulk or exfoliated-restacked MoS2. Transmission electron microscopy studies reveal that the interconnected MoS2 nanocrystals created during the phase change process are reformable even after multiple cycles of galvanostatic charging/discharging, which allows them to play important roles in the long term cycling performance of the chemically intercalated TMD materials. These studies shed light on how bulk TMDs can be processed into quasi-2D nanophase material for stable energy storage.
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Cites
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034
Self-citationHigh yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide
Zheng, J., Zhang, H., Dong, S., Liu, Y., Tai Nai, C., Suk Shin, H., Young Jeong, H., Liu, B., & Ping Loh, K. (2014) · Nature Communications · doi:10.1038/ncomms3995 · Cited by 787
Cited by
Ionic modulation and ionic coupling effects in MoS2 devices for neuromorphic computing
Zhu, X., Li, D., Liang, X., & Lu, W. D. (2019) · Nature Materials · doi:10.1038/s41563-018-0248-5 · Cited by 640
Recent Development of Metallic (1T) Phase of Molybdenum Disulfide for Energy Conversion and Storage
Lei, Z., Zhan, J., Tang, L., Zhang, Y., & Wang, Y. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703482 · Cited by 485
Structural Engineering of 2D Nanomaterials for Energy Storage and Catalysis
Zhu, Y., Peng, L., Fang, Z., Yan, C., Zhang, X., & Yu, G. (2018) · Advanced Materials · doi:10.1002/adma.201706347 · Cited by 451
Synthesis, stabilization and applications of 2-dimensional 1T metallic MoS 2
Shi, S., Sun, Z., & Hu, Y. H. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta08152b · Cited by 374
2D Metallic Transition‐Metal Dichalcogenides: Structures, Synthesis, Properties, and Applications
Zhao, B., Shen, D., Zhang, Z., Lu, P., Hossain, M., Li, J., Li, B., & Duan, X. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202105132 · Cited by 359
Metadata
- Authors
- Leng, K., Chen, Z., Zhao, X., Tang, W., Tian, B., Nai, C. T., Zhou, W., & Loh, K. P.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-09-28
- Volume
- 10
- Issue
- 10
- Pages
- 9208-9215
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2520090679
- Cited by
- 270
- References
- 2
- FWCI
- 10.98
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Leng, K., Chen, Z., Zhao, X., Tang, W., Tian, B., Nai, C. T., Zhou, W., & Loh, K. P. (2016). Phase Restructuring in Transition Metal Dichalcogenides for Highly Stable Energy Storage. ACS Nano. https://doi.org/10.1021/acsnano.6b05746
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