The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
ZnS-Sb2S3@C Core-Double Shell Polyhedron Structure Derived from Metal–Organic Framework as Anodes for High Performance Sodium Ion Batteries
Abstract
Taking advantage of zeolitic imidazolate framework (ZIF-8), ZnS-Sb 2 S 3 @C core-double shell polyhedron structure is synthesized through a sulfurization reaction between Zn 2+ dissociated from ZIF-8 and S 2– from thioacetamide (TAA), and subsequently a metal cation exchange process between Zn 2+ and Sb 3+, in which carbon layer is introduced from polymeric resorcinol-formaldehyde to prevent the collapse of the polyhedron. The polyhedron composite with a ZnS inner-core and Sb 2 S 3 /C double-shell as anode for sodium ion batteries (SIBs) shows us a significantly improved electrochemical performance with stable cycle stability, high Coulombic efficiency and specific capacity. Peculiarly, introducing a carbon shell not only acts as an important protective layer to form a rigid construction and accommodate the volume changes, but also improves the electronic conductivity to optimize the stable cycle performance and the excellent rate property. The architecture composed of ZnS inner core and a complex Sb 2 S 3 /C shell not only facilitates the facile electrolyte infiltration to reduce the Na-ion diffusion length to improve the electrochemical reaction kinetics, but also prevents the structure pulverization caused by Na-ion insertion/extraction. This approach to prepare metal sulfides based on MOFs can be further extended to design other nanostructured systems for high performance energy storage devices.
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Cites
A phosphorene–graphene hybrid material as a high-capacity anode for sodium-ion batteries
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Preparation and Properties of Resorcinol–Formaldehyde Organic and Carbon Gels
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Self-citationGe, X., Li, Z., & Yin, L. (2017) · Nano Energy · doi:10.1016/j.nanoen.2016.11.055 · Cited by 457
Self-citationZhang, K., Park, M., Zhou, L., Lee, G., Shin, J., Hu, Z., Chou, S., Chen, J., & Kang, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201607469 · Cited by 449
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Cited by
Fang, G., Wang, Q., Zhou, J., Lei, Y., Chen, Z., Wang, Z., Pan, A., & Liang, S. (2019) · ACS Nano · doi:10.1021/acsnano.9b00816 · Cited by 507
Metal–Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion
Zhang, X., Chen, A., Zhong, M., Zhang, Z., Zhang, X., Zhou, Z., & Bu, X.-H. (2019) · Electrochemical Energy Reviews · doi:10.1007/s41918-018-0024-x · Cited by 481
Rational Design of MOF-Based Materials for Next-Generation Rechargeable Batteries
Ye, Z., Jiang, Y., Li, L., Wu, F., & Chen, R. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00726-z · Cited by 323
Beyond Insertion for Na‐Ion Batteries: Nanostructured Alloying and Conversion Anode Materials
Zhang, H., Hasa, I., & Passerini, S. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702582 · Cited by 316
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Metadata
- Authors
- Dong, S., Li, C., Ge, X., Li, Z., Miao, X., & Yin, L.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-13
- Volume
- 11
- Issue
- 6
- Pages
- 6474-6482
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2622166976
- Cited by
- 371
- References
- 33
- FWCI
- 18.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dong, S., Li, C., Ge, X., Li, Z., Miao, X., & Yin, L. (2017). ZnS-Sb2S3@C Core-Double Shell Polyhedron Structure Derived from Metal–Organic Framework as Anodes for High Performance Sodium Ion Batteries. ACS Nano. https://doi.org/10.1021/acsnano.7b03321
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