The DOI matches its Crossref record; 49 of the 49 references it cites were found in a registry or an index.
Double‐Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High‐Efficiency Polysulfide Mediator for Lithium–Sulfur Batteries
Abstract
Lithium–sulfur (Li‐S) batteries have been considered as a promising candidate for next‐generation electrochemical energy‐storage technologies because of their overwhelming advantages in energy density. Suppression of the polysulfide dissolution while maintaining a high sulfur utilization is the main challenge for Li–S batteries. Here, we have designed and synthesized double‐shelled nanocages with two shells of cobalt hydroxide and layered double hydroxides (CH@LDH) as a conceptually new sulfur host for Li–S batteries. Specifically, the hollow CH@LDH polyhedra with complex shell structures not only maximize the advantages of hollow nanostructures for encapsulating a high content of sulfur (75 wt %), but also provide sufficient self‐functionalized surfaces for chemically bonding with polysulfides to suppress their outward dissolution. When evaluated as cathode material for Li–S batteries, the CH@LDH/S composite shows a significantly improved electrochemical performance.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
Ji, X., Lee, K. T., & Nazar, L. F. (2009) · Nature Materials · doi:10.1038/nmat2460 · Cited by 5,988
Rechargeable Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., Chung, S.-H., Zu, C., & Su, Y.-S. (2014) · Chemical Reviews · doi:10.1021/cr500062v · Cited by 4,665
Recent Advances in the Synthesis and Application of Layered Double Hydroxide (LDH) Nanosheets
Wang, Q., & O’Hare, D. (2012) · Chemical Reviews · doi:10.1021/cr200434v · Cited by 3,511
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
Suo, L., Hu, Y.-S., Li, H., Armand, M., & Chen, L. (2013) · Nature Communications · doi:10.1038/ncomms2513 · Cited by 2,314
A highly efficient polysulfide mediator for lithium–sulfur batteries
Liang, X., Hart, C., Pang, Q., Garsuch, A., Weiss, T., & Nazar, L. F. (2015) · Nature Communications · doi:10.1038/ncomms6682 · Cited by 2,062
Ji, X., & Nazar, L. F. (2010) · Journal of Materials Chemistry · doi:10.1039/b925751a · Cited by 1,967
Nanostructured sulfur cathodes
Yang, Y., Zheng, G., & Cui, Y. (2013) · Chemical Society Reviews · doi:10.1039/c2cs35256g · Cited by 1,947
Porous Hollow Carbon@Sulfur Composites for High‐Power Lithium–Sulfur Batteries
Jayaprakash, N., Shen, J., Moganty, S. S., Corona, A., & Archer, L. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100637 · Cited by 1,811
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
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Cited by
Guan, B. Y., Yu, X. Y., Wu, H. B., & Lou, X. W. (. (2017) · Advanced Materials · doi:10.1002/adma.201703614 · Cited by 733
Self-citationA sulfur host based on titanium monoxide@carbon hollow spheres for advanced lithium–sulfur batteries
Li, Z., Zhang, J., Guan, B., Wang, D., Liu, L.-M., & Lou, X. W. (2016) · Nature Communications · doi:10.1038/ncomms13065 · Cited by 677
Self-citationLithium Bond Chemistry in Lithium–Sulfur Batteries
Hou, T., Xu, W., Chen, X., Peng, H., Huang, J., & Zhang, Q. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201704324 · Cited by 574
Lu, X. F., Fang, Y., Luan, D., & Lou, X. W. D. (2021) · Nano Letters · doi:10.1021/acs.nanolett.0c04898 · Cited by 555
Self-citationNg, S., Lau, M. Y. L., & Ong, W. (2021) · Advanced Materials · doi:10.1002/adma.202008654 · Cited by 404
Metadata
- Authors
- Zhang, J., Hu, H., Li, Z., & Lou, X. W. (.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-02-19
- Volume
- 55
- Issue
- 12
- Pages
- 3982-3986
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2284684952
- Cited by
- 560
- References
- 49
- FWCI
- 48.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, J., Hu, H., Li, Z., & Lou, X. W. (. (2016). Double‐Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High‐Efficiency Polysulfide Mediator for Lithium–Sulfur Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201511632
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