The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Flexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide
Abstract
Although both are based on Zn, Zn–air batteries and Zn–ion batteries are good at energy density and power density, respectively. Here, we adopted Ar–plasma to engrave a cobalt oxide with abundant oxygen vacancies (denoted as Co 3 O 4– x ). The introduction of oxygen vacancies to cobalt oxide not only promotes its reversible Co–O ↔ Co–O–OH redox reaction but also leads to good oxygen reduction reaction and oxygen evolution (ORR/OER) performance (a half-wave potential of 0.84 V, four-electron transfer process for ORR, and 330 mV overpotential, 58 mV·dec –1 Tafel slope for OER). We then constructed a battery system based on both Zn–Co 3 O 4– x and Zn–air electrochemical reactions. The hybrid battery reveals both a high-power density of 3200 W·kg –1 and high-energy density of 1060 Wh·kg –1 . Furthermore, the developed flexible solid-state hybrid batterydemonstrates good waterproof and washable ability (99.2% capacity retention of after 20 h water soaking test and 93.2% capacity retention after 1 h washing test). Interestingly, the fabricated flexible battery can work under water, and after the power is exhausted, the battery can automatically recover electricity output as long as it is exposed to air. The developed device is suitable for wearable applications considering its electrochemical performances, great environmental adaptation, and “air recoverability”. In addition, this study underscores the approach to develop hybrid energy-storage technologies through modification of electrode materials.
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Citations
Cites
A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions
Zhang, J., Zhao, Z., Xia, Z., & Dai, L. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.48 · Cited by 3,094
Recent advances in zinc–air batteries
Li, Y., & Dai, H. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00015c · Cited by 2,315
Hybrid energy storage: the merging of battery and supercapacitor chemistries
Dubal, D. P., Ayyad, O., Ruiz, V., & Gómez-Romero, P. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00266k · Cited by 2,180
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x
Kim, H.-S., Cook, J. B., Lin, H., Ko, J. S., Tolbert, S. H., Ozolins, V., & Dunn, B. (2017) · Nature Materials · doi:10.1038/nmat4810 · Cited by 2,166
Battery‐Supercapacitor Hybrid Devices: Recent Progress and Future Prospects
Zuo, W., Li, R., Zhou, C., Li, Y., Xia, J., & Liu, J. (2017) · Advanced Science · doi:10.1002/advs.201600539 · Cited by 1,637
Wang, J., Huang, Z., Liu, W., Chang, C., Tang, H., Li, Z., Chen, W., Jia, C., Yao, T., Wei, S., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b10385 · Cited by 1,596
Advanced zinc-air batteries based on high-performance hybrid electrocatalysts
Li, Y., Gong, M., Liang, Y., Feng, J., Kim, J.-E., Wang, H., Hong, G., Zhang, B., & Dai, H. (2013) · Nature Communications · doi:10.1038/ncomms2812 · Cited by 1,175
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Cited by
Xiao, Z., Huang, Y.-C., Dong, C.-L., Xie, C., Liu, Z., Du, S., Chen, W., Yan, D., Tao, L., Shu, Z., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00257 · Cited by 1,445
Self-citationThe roles of oxygen vacancies in electrocatalytic oxygen evolution reaction
Zhu, K., Shi, F., Zhu, X., & Yang, W. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.104761 · Cited by 1,018
A flexible rechargeable aqueous zinc manganese-dioxide battery working at −20 °C
Mo, F., Liang, G., Meng, Q., Liu, Z., Li, H., Fan, J., & Zhi, C. (2019) · Energy & Environmental Science · doi:10.1039/c8ee02892c · Cited by 687
Self-citationDiao, J., Qiu, Y., Liu, S., Wang, W., Chen, K., Li, H., Yuan, W., Qu, Y., & Guo, X. (2020) · Advanced Materials · doi:10.1002/adma.201905679 · Cited by 555
Self-citationWu, K., Huang, J., Yi, J., Liu, X., Liu, Y., Wang, Y., Zhang, J., & Xia, Y. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903977 · Cited by 522
Metadata
- Authors
- Ma, L., Chen, S., Pei, Z., Li, H., Wang, Z., Liu, Z., Tang, Z., Zapien, J. A., & Zhi, C.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-07-24
- Volume
- 12
- Issue
- 8
- Pages
- 8597-8605
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2884183711
- Cited by
- 317
- References
- 35
- FWCI
- 15.71
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ma, L., Chen, S., Pei, Z., Li, H., Wang, Z., Liu, Z., Tang, Z., Zapien, J. A., & Zhi, C. (2018). Flexible Waterproof Rechargeable Hybrid Zinc Batteries Initiated by Multifunctional Oxygen Vacancies-Rich Cobalt Oxide. ACS Nano. https://doi.org/10.1021/acsnano.8b04317
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