Carbon Nanotubes and Related Nanomaterials: Critical Advances and Challenges for Synthesis toward Mainstream Commercial Applications
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Advances in the synthesis and scalable manufacturing of single-walled carbon nanotubes (SWCNTs) remain critical to realizing many important commercial applications. Here we review recent breakthroughs in the synthesis of SWCNTs and highlight key ongoing research areas and challenges. A few key applications that capitalize on the properties of SWCNTs are also reviewed with respect to the recent synthesis breakthroughs and ways in which synthesis science can enable advances in these applications. While the primary focus of this review is on the science framework of SWCNT growth, we draw connections to mechanisms underlying the synthesis of other 1D and 2D materials such as boron nitride nanotubes and graphene.
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Carbon nanotube optical and electronic properties, such as bandgaps, depend sensitively on layer number, chiral indices, and tube diameter.
“Carbon nanotubes are high aspect ratio cylinders of graphene with typical microscale lengths and nanoscale diameters, which can be single- or multi-walled and exhibit optical and electronic properties (e.g., bandgaps) that depend sensitively on layer number, chiral indices, and tube diameter226.”
From Ultrafast terahertz emission from emerging symmetry-broken materials (2023) · cites this paper as [226]
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Mazari, S. A., Ali, E., Abro, R., Khan, F. S. A., Ahmed, I., Ahmed, M., Nizamuddin, S., Siddiqui, T. H., Hossain, N., Mubarak, N. M., et al. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105028 · Cited by 316 · see citing works
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- Authors
- Rao, R., Pint, C. L., Islam, A. E., Weatherup, R. S., Hofmann, S., Meshot, E. R., Wu, F., Zhou, C., Dee, N., Amama, P. B., Carpena-Nuñez, J., Shi, W., Plata, D. L., Penev, E. S., Yakobson, B. I., Balbuena, P. B., Bichara, C., Futaba, D. N., Noda, S., Shin, H., Kim, K. S., Simard, B., Mirri, F., Pasquali, M., Fornasiero, F., Kauppinen, E. I., Arnold, M., Cola, B. A., Nikolaev, P., Arepalli, S., Cheng, H.-M., Zakharov, D. N., Stach, E. A., Zhang, J., Wei, F., Terrones, M., Geohegan, D. B., Maruyama, B., Maruyama, S., Li, Y., Adams, W. W., & Hart, A. J.
- Affiliations
- United States Air Force Research Laboratory (US)
- Vanderbilt University (US)
- Diamond Light Source (GB)
- University of Cambridge (GB)
- Lawrence Livermore National Laboratory (US)
- University of Southern California (US)
- Massachusetts Institute of Technology (US)
- Kansas State University (US)
- Wright Patterson Air Force Base , , , ,
- Yale University (US)
- Massachusetts Institute of Technology , , , ,
- Rice University (US)
- Texas A&M University (US)
- Centre National de la Recherche Scientifique (FR)
- National Institute of Advanced Industrial Science and Technology (JP)
- Waseda University (JP)
- National Research Council Canada (CA)
- National Research Council Canada , , , ,
- Rice University , , , ,
- Aalto University (FI)
- University of Wisconsin–Madison (US)
- Georgia Institute of Technology (US)
- Chinese Academy of Sciences (CN)
- Brookhaven National Laboratory (US)
- University of Pennsylvania (US)
- Peking University (CN)
- Tsinghua University (CN)
- Pennsylvania State University (US)
- Oak Ridge National Laboratory (US)
- The University of Tokyo (JP)
- Corresponding author
- Rao, Rahul
- ORCID
- Rao, Rahul
- Pint, Cary L.
- Islam, Ahmad E.
- Weatherup, Robert S.
- Hofmann, Stephan
- Meshot, Eric R.
- Wu, Fanqi
- Zhou, Chongwu
- Dee, Nicholas
- Amama, Placidus B.
- Shi, Wenbo
- Penev, Evgeni S.
- Yakobson, Boris I.
- Balbuena, Perla B.
- Bichara, Christophe
- Futaba, Don N.
- Noda, Suguru
- Shin, Homin
- Kim, Keun Su
- Mirri, Francesca
- Pasquali, Matteo
- Fornasiero, Francesco
- Kauppinen, Esko I.
- Arnold, Michael
- Cola, Baratunde A.
- Arepalli, Sivaram
- Cheng, Hui-Ming
- Zakharov, Dmitri N.
- Stach, Eric A.
- Zhang, Jin
- Wei, Fei
- Terrones, Mauricio
- Geohegan, David B.
- Maruyama, Benji
- Maruyama, Shigeo
- Li, Yan
- Hart, A. John
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-05
- Volume
- 12
- Issue
- 12
- Pages
- 11756-11784
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2903561922
- Cited by
- 588
- References
- 452
- Citations by year
- 2026: 55 · 2025: 59 · 2024: 87 · 2023: 77 · 2022: 99 · 2021: 99 · 2020: 72 · 2019: 38 · 2018: 1
- FWCI
- 19.69
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- ACS Nano (publishedVersion, other-oa)
- PubMed (publishedVersion)
- Aaltodoc (Aalto University) (submittedVersion, cc-by-nc)
- NPARC (submittedVersion, cc-by-nc)
- HAL (submittedVersion)
- DSpace@MIT (Massachusetts Institute of Technology) (submittedVersion, cc-by-nc)
- Cambridge University Engineering Department Publications Database (submittedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Rice Research Repository (Rice University) (submittedVersion, other-oa)
- Funders
- Office of Naval Research (NA)
- Division of Chemical, Bioengineering, Environmental, and Transport Systems (CBET-1605848)
- Air Force Office of Scientific Research (FA9550-14-1-0107, LRIR 16RXCOR322)
- Welch Foundation (C-1590)
- Basic Energy Sciences (DE-FG02-06ER15836)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Carbon Nanotubes in Composites
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Materials Science › Materials Chemistry › Boron and Carbon Nanomaterials Research
- Keywords
- single-walled carbon nanotubes, carbon nanotube synthesis, scalable fabrication, nanotube growth mechanism, boron nitride nanotubes, graphene
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