The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Role of Sulfur Vacancies and Undercoordinated Mo Regions in MoS2 Nanosheets toward the Evolution of Hydrogen
Open accessAbstract
Low-dimensional materials have been examined as electrocatalysts for the hydrogen evolution reaction (HER). Among them, two-dimensional transition metal dichalcogenides (2D-TMDs) such as MoS 2 have been identified as potential candidates. However, the performance of TMDs toward HER in both acidic and basic media remains inferior to that of noble metals such as Pt and its alloys. This calls for investigating the influence of controlled defect engineering of 2D TMDs on their performance toward hydrogen production. Here, we explored the HER activity from defective multilayered MoS 2 over a large range of surface S vacancy concentrations up to 90%. Amorphous MoS 2 and 2H MoS 2 with ultrarich S vacancies demonstrated the highest HER performance in acid and basic electrolytes, respectively. We also report that the HER performance from multilayered MoS 2 can be divided into two domains corresponding to “point defects” at low concentrations of surface S vacancies (Stage 1) and large regions of undercoordinated Mo atoms for high concentrations of surface S vacancies (Stage 2). The highest performance is obtained for Stage 2 in the presence of undercoordinated Mo atoms with a TOF of ∼2 s –1 at an overpotential of 160 mV in 0.1 M KOH which compares favorably to the best results in the literature. Overall, our work provides deeper insight on the HER mechanism from defected MoS 2 and provides guidance for the development of defect-engineered TMD-based electrocatalysts.
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Cites
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641
Self-citationPartially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
Self-citationJiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
Voiry, D., Fullon, R., Yang, J., de Carvalho Castro e Silva, C., Kappera, R., Bozkurt, I., Kaplan, D., Lagos, M. J., Batson, P. E., Gupta, G., et al. (2016) · Nature Materials · doi:10.1038/nmat4660 · Cited by 824
Self-citationShi, J., Ma, D., Han, G.-F., Zhang, Y., Ji, Q., Gao, T., Sun, J., Song, X., Li, C., Zhang, Y., et al. (2014) · ACS Nano · doi:10.1021/nn503211t · Cited by 459
Component-Controllable WS2(1– x )Se2 x Nanotubes for Efficient Hydrogen Evolution Reaction
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Cited by
Precious Metal Free Hydrogen Evolution Catalyst Design and Application
Feidenhans’l, A. A., Regmi, Y. N., Wei, C., Xia, D., Kibsgaard, J., & King, L. A. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00712 · Cited by 499
Design Strategies for Development of TMD-Based Heterostructures in Electrochemical Energy Systems
Prabhu, P., Jose, V., & Lee, J.-M. (2020) · Matter · doi:10.1016/j.matt.2020.01.001 · Cited by 460
Rational Design of Better Hydrogen Evolution Electrocatalysts for Water Splitting: A Review
Liu, F., Shi, C., Guo, X., He, Z., Pan, L., Huang, Z., Zhang, X., & Zou, J. (2022) · Advanced Science · doi:10.1002/advs.202200307 · Cited by 455
Defect engineering of two-dimensional materials for advanced energy conversion and storage
Liu, F., & Fan, Z. (2023) · Chemical Society Reviews · doi:10.1039/d2cs00931e · Cited by 417
Roadmap and Direction toward High-Performance MoS 2 Hydrogen Evolution Catalysts
Cao, Y. (2021) · ACS Nano · doi:10.1021/acsnano.1c01879 · Cited by 405
Metadata
- Authors
- Li, L., Qin, Z., Ries, L., Hong, S., Michel, T., Yang, J., Salameh, C., Bechelany, M., Miele, P., Kaplan, D., Chhowalla, M., & Voiry, D.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-05-28
- Volume
- 13
- Issue
- 6
- Pages
- 6824-6834
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2946992377
- Cited by
- 626
- References
- 8
- FWCI
- 15.05
- Type
- journal article
- Language
- en
- Open access
- green
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