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Cited by 455Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsFuel Cells and Related Materials

Rational Design of Better Hydrogen Evolution Electrocatalysts for Water Splitting: A Review

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Liu, Fan, Shi, Chengxiang, Guo, Xiaolei, He, Zexing, Pan, Lun, Huang, Zhen‐Feng, Zhang, Xiangwen, Zou, Ji‐Jun·2022·Advanced Science
DOI 10.1002/advs.202200307PMC PMC9218766
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Abstract

The excessive dependence on fossil fuels contributes to the majority of CO 2 emissions, influencing on the climate change. One promising alternative to fossil fuels is green hydrogen, which can be produced through water electrolysis from renewable electricity. However, the variety and complexity of hydrogen evolution electrocatalysts currently studied increases the difficulty in the integration of catalytic theory, catalyst design and preparation, and characterization methods. Herein, this review first highlights design principles for hydrogen evolution reaction (HER) electrocatalysts, presenting the thermodynamics, kinetics, and related electronic and structural descriptors for HER. Second, the reasonable design, preparation, mechanistic understanding, and performance enhancement of electrocatalysts are deeply discussed based on intrinsic and extrinsic effects. Third, recent advancements in the electrocatalytic water splitting technology are further discussed briefly. Finally, the challenges and perspectives of the development of highly efficient hydrogen evolution electrocatalysts for water splitting are proposed.

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  • High costs and limited availability of Pt have motivated researchers to explore strategies for electrocatalysts with reduced Pt content.

    “High costs and limited availability of Pt have motivated researchers to explore various strategies for the development of electrocatalysts with reduced Pt content.[10–13]”

    From Synthesis of Pt Carbon Aerogel Electrocatalysts with Multiscale Porosity Derived from Cellulose and Chitosan Biopolymer Aerogels via Supercritical Deposition for Hydrogen Evolution Reaction (2025) · cites this paper as [13]

    The review’s “Strategies to Improve HER Electrocatalysts > Intrinsic Effect” section discusses cost reduction through Pt-based alloys and gives an example of a low-Pt-content catalyst. Its “Applications of HER Electrocatalysts” section also says expensive precious-metal catalysts increase costs. The passages do not establish limited Pt availability as a motivation, so that part of the claim is unsupported. (LLM, conf=0.82)

    Experimental — accuracy not yet measured

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200 of 294 shown

Cited by

Sorted by citations

Authors
Liu, F., Shi, C., Guo, X., He, Z., Pan, L., Huang, Z., Zhang, X., & Zou, J.
Affiliations
Tianjin University (CN)
Corresponding author
  • Huang, Zhen‐Feng
  • Zou, Ji‐Jun
ORCID
Venue
Advanced Science
Publisher
Wiley
Published
2022-04-18
Volume
9
Issue
18
Pages
e2200307-e2200307
ISSN
2198-3844 (ISSN-L)
DOI
10.1002/advs.202200307
PMC
PMC9218766
OpenAlex
W4224013593
Cited by
455
References
22
Citations by year
2026: 78 · 2025: 120 · 2024: 143 · 2023: 91 · 2022: 23
FWCI
5.98
Type
journal article
Language
en
Open access
Licence
Locations
  • Advanced Science (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
Funders
National Natural Science Foundation of China (2200080551, 21978200, 22161142002, 22121004)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
Keywords
hydrogen evolution reaction, electrocatalysts, water splitting, water electrolysis, green hydrogen, catalyst design, reaction kinetics, thermodynamics, catalyst preparation, reaction mechanism

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