The DOI matches its Crossref record; 58 of the 58 references it cites were found in a registry or an index.
Photochemical Reduction of CO2 Using TiO2: Effects of Organic Adsorbates on TiO2 and Deposition of Pd onto TiO2
Open accessAbstract
Reduction of CO(2) using semiconductors as photocatalysts has recently attracted a great deal of attention again. The effects of organic adsorbates on semiconductors on the photocatalytic products are noteworthy. On untreated TiO(2) (P-25) particles a considerable number of organic molecules such as acetic acid were adsorbed. Although irradiation of an aqueous suspension of this TiO(2) resulted in the formation of a significant amount of CH(4) as a major product, it was strongly suggested that its formation mainly proceeded via the photo-Kolbe reaction of acetic acid. Using TiO(2) treated by calcination and washing procedures for removal of the organic adsorbates, CO was photocatalytically generated as a major product, along with a very small amount of CH(4), from an aqueous suspension under a CO(2) atmosphere. In contrast, by using Pd (>0.5 wt %) deposited on TiO(2) (Pd-TiO(2)) on which organic adsorbates were not detected, CH(4) was the main product, but CO formation was drastically reduced compared with that on the pretreated TiO(2). Experimental data, including isotope labeling, indicated that CO(2) and CO(3)(2-) are the main carbon sources of the CH(4) formation, which proceeds on the Pd site of Pd-TiO(2). Prolonged irradiation caused deactivation of the photocatalysis of Pd-TiO(2) because of the partial oxidation of the deposited Pd to PdO.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Handbook of X-Ray Photoelectron Spectroscopy
Moulder, J. F. (1995) · Medical Entomology and Zoology · Cited by 23,662
Titanium dioxide photocatalysis
Fujishima, A., Rao, T. N., & Tryk, D. A. (2000) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/s1389-5567(00)00002-2 · Cited by 7,916
Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders
INOUE, T., FUJISHIMA, A., KONISHI, S., & HONDA, K. (1979) · Nature · doi:10.1038/277637a0 · Cited by 2,919
Photocatalyst releasing hydrogen from water
Maeda, K., Teramura, K., Lu, D., Takata, T., Saito, N., Inoue, Y., & Domen, K. (2006) · Nature · doi:10.1038/440295a · Cited by 2,812
Kato, H., Asakura, K., & Kudo, A. (2003) · Journal of the American Chemical Society · doi:10.1021/ja027751g · Cited by 1,705
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons
Roy, S. C., Varghese, O. K., Paulose, M., & Grimes, C. A. (2010) · ACS Nano · doi:10.1021/nn9015423 · Cited by 1,513
Abe, R. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.003 · Cited by 1,223
Visible Light Water Splitting Using Dye-Sensitized Oxide Semiconductors
Youngblood, W. J., Lee, S.-H. A., Maeda, K., & Mallouk, T. E. (2009) · Accounts of Chemical Research · doi:10.1021/ar9002398 · Cited by 1,011
Photocatalysis A to Z—What we know and what we do not know in a scientific sense
Ohtani, B. (2010) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/j.jphotochemrev.2011.02.001 · Cited by 749
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Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
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Kuhl, K. P., Hatsukade, T., Cave, E. R., Abram, D. N., Kibsgaard, J., & Jaramillo, T. F. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505791r · Cited by 1,649
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
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Park, H., Kim, H.-I., Moon, G.-H., & Choi, W. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02575c · Cited by 582
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Metadata
- Authors
- Yui, T., Kan, A., Saitoh, C., Koike, K., Ibusuki, T., & Ishitani, O.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-21
- Volume
- 3
- Issue
- 7
- Pages
- 2594-2600
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2323604837
- Cited by
- 308
- References
- 58
- FWCI
- 9.59
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Yui, T., Kan, A., Saitoh, C., Koike, K., Ibusuki, T., & Ishitani, O. (2011). Photochemical Reduction of CO2 Using TiO2: Effects of Organic Adsorbates on TiO2 and Deposition of Pd onto TiO2. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am200425y
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