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Synthesis of Cobalt Phosphides and Their Application as Anodes for Lithium Ion Batteries
Abstract
A facile thermal decomposing method has been developed for the fabrication of Co(x)P nanostructures with controlled size, phase, and shape (e.g., Co(2)P rod and spheres, CoP hollow and solid particles). An amorphous carbon layer could be introduced by the carbonization of organic surfactants from the precursors. The electrochemical performance of typical CoP and Co(2)P samples as anode materials has been investigated and the CoP hollow nanoparticle with carbon coating layer depicts good capacity retention and high rate capability (e.g., specific capacity of 630 mA h g(-1) at 0.2 C after 100 cycles, and a reversible capacity of 256 mA h g(-1) can be achieved at a high current rate of 5 C).
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Cited by
Review on recent progress of nanostructured anode materials for Li-ion batteries
Goriparti, S., Miele, E., De Angelis, F., Di Fabrizio, E., Proietti Zaccaria, R., & Capiglia, C. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.11.103 · Cited by 2,092
Ryu, J., Jung, N., Jang, J. H., Kim, H.-J., & Yoo, S. J. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00349 · Cited by 455
Li3V2(PO4)3 cathode materials for lithium-ion batteries: A review
Rui, X., Yan, Q., Skyllas-Kazacos, M., & Lim, T. M. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.01.126 · Cited by 342
Self-citationQiu, S., Xing, W., Mu, X., Feng, X., Ma, C., Yuen, R. K. K., & Hu, Y. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b11101 · Cited by 58
Metadata
- Authors
- Yang, D., Zhu, J., Rui, X., Tan, H., Cai, R., Hoster, H. E., Yu, D. Y. W., Hng, H. H., & Yan, Q.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-24
- Volume
- 5
- Issue
- 3
- Pages
- 1093-1099
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2150887763
- Cited by
- 185
- References
- 0
- FWCI
- 7.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, D., Zhu, J., Rui, X., Tan, H., Cai, R., Hoster, H. E., Yu, D. Y. W., Hng, H. H., & Yan, Q. (2013). Synthesis of Cobalt Phosphides and Their Application as Anodes for Lithium Ion Batteries. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am302877q
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