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Solvothermal One-Step Synthesis of Ni–Al Layered Double Hydroxide/Carbon Nanotube/Reduced Graphene Oxide Sheet Ternary Nanocomposite with Ultrahigh Capacitance for Supercapacitors
Abstract
A Ni-Al layered double hydroxide (LDH), mutil-wall carbon nanotube (CNT), and reduced graphene oxide sheet (GNS) ternary nanocomposite electrode material has been developed by a facile one-step ethanol solvothermal method. The obtained LDH/CNT/GNS composite displayed a three-dimensional (3D) architecture with flowerlike Ni-Al LDH/CNT nanocrystallites gradually self-assembled on GNS nanosheets. GNS was used as building blocks to construct 3D nanostructure, and the LDH/CNT nanoflowers in turn separated the two-dimensional (2D) GNS sheets, which preserved the high surface area of GNSs. Furthermore, the generated porous networks with a narrow pore size distribution in the LDH/CNT/GNS composite were also demonstrated by the N2 adsorption/desorption experiment. Such morphology would be favorable to improve the mass transfer and electrochemical action of the electrode. As supercapacitor electrode material, the LDH/CNT/GNS hybrid exhibited excellent electrochemical performance, including ultrahigh specific capacitance (1562 F/g at 5 mA/cm(2)), excellent rate capability, and long-term cycling performance, which could be a promising energy storage/conversion material for supercapacitor application.
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Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Gao, Z., Wang, J., Li, Z., Yang, W., Wang, B., Hou, M., He, Y., Liu, Q., Mann, T., Yang, P., et al. (2011) · Chemistry of Materials · doi:10.1021/cm200975x · Cited by 542
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Gao, Z., Yang, W., Wang, J., Song, N., & Li, X. (2015) · Nano Energy · doi:10.1016/j.nanoen.2015.02.036 · Cited by 337
Self-citationLi, Z., Niu, W., Zhou, L., & Yang, Y. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00174 · Cited by 162
Memon, J., Sun, J., Meng, D., Ouyang, W., Memon, M. A., Huang, Y., Yan, S., & Geng, J. (2014) · Journal of Materials Chemistry A · doi:10.1039/c3ta14613h · Cited by 135
Metadata
- Authors
- Yang, W., Gao, Z., Wang, J., Ma, J., Zhang, M., & Liu, L.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-05
- Volume
- 5
- Issue
- 12
- Pages
- 5443-5454
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2005963921
- Cited by
- 272
- References
- 2
- FWCI
- 9.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, W., Gao, Z., Wang, J., Ma, J., Zhang, M., & Liu, L. (2013). Solvothermal One-Step Synthesis of Ni–Al Layered Double Hydroxide/Carbon Nanotube/Reduced Graphene Oxide Sheet Ternary Nanocomposite with Ultrahigh Capacitance for Supercapacitors. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am4003843
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