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Efficient Visible-Light Photocatalytic Hydrogen Evolution and Enhanced Photostability of Core/Shell CdS/g-C3N4Nanowires
Abstract
CdS/g-C3N4 core/shell nanowires with different g-C3N4 contents were fabricated by a combined solvothermal and chemisorption method and characterized by X-ray powder diffraction, scanning electronic microscopy, transmission electron microscopy, and UV-vis diffuse reflection spectroscopy. The photocatalytic hydrogen-production activities of these samples were evaluated using Na2S and Na2SO3 as sacrificial reagents in water under visible-light illumination (λ≥420 nm). The results show that after a spontaneous adsorption process g-C3N4 is successfully coated on CdS nanowires with intimate contact and can significantly improve the photocatalytic hydrogen-production rate of CdS nanowires, which reaches an optimal value of up to 4152 μmol h(-1) g(-1) at the g-C3N4 content of 2 wt %. More importantly, g-C3N4 coating can substantially reinforce the photostability of CdS nanowires even in a nonsacrificial system. The synergic effect between g-C3N4 and CdS, which can effectively accelerate the charge separation and transfer corrosive holes from CdS to robust C3N4, was proposed to be responsible for the enhancement of the photocatalytic activity and photostability. The possible conditions necessary for the synergic effect to work in a CdS/g-C3N4 core/shell configuration is also discussed.
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Cites
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Ren, Y., Zeng, D., & Ong, W.-J. (2019) · Chinese Journal of Catalysis · doi:10.1016/s1872-2067(19)63293-6 · Cited by 528
Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production
Yuan, Y.-J., Chen, D., Yu, Z.-T., & Zou, Z.-G. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00671g · Cited by 523
Li, W., Feng, C., Dai, S., Yue, J., Hua, F., & Hou, H. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.01.012 · Cited by 344
Li, K., Han, M., Chen, R., Li, S., Xie, S., Mao, C., Bu, X., Cao, X., Dong, L., Feng, P., et al. (2016) · Advanced Materials · doi:10.1002/adma.201601047 · Cited by 312
Metadata
- Authors
- Zhang, J., Wang, Y., Jin, J., Zhang, J., Lin, Z., Huang, F., & Yu, J.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-10-08
- Volume
- 5
- Issue
- 20
- Pages
- 10317-10324
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2317693325
- Cited by
- 807
- References
- 2
- FWCI
- 22.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhang, J., Wang, Y., Jin, J., Zhang, J., Lin, Z., Huang, F., & Yu, J. (2013). Efficient Visible-Light Photocatalytic Hydrogen Evolution and Enhanced Photostability of Core/Shell CdS/g-C3N4Nanowires. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am403327g
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