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Temperature Dependent Phonon Shifts in Single-Layer WS2

M, Thripuranthaka, Late, Dattatray J.·2014·ACS Applied Materials & Interfaces

Abstract

Atomically thin two-dimensional tungsten disulfide (WS2) sheets have attracted much attention due to their potential for future nanoelectronic device applications. We report first experimental investigation on temperature dependent Raman spectra of single-layer WS2 prepared using micromechanical exfoliation. Our temperature dependent Raman spectroscopy results shows that the E(1)2g and A1g modes of single-layer WS2 soften as temperature increases from 77 to 623 K. The calculated temperature coefficients of the frequencies of 2LA(M), E(1)2g, A1g, and A1g(M) + LA(M) modes of single-layer WS2 were observed to be -0.008, -0.006, -0.006, and -0.01 cm(-1) K(-1), respectively. The results were explained in terms of a double resonance process which is active in atomically thin nanosheet. This process can also be largely applicable in other emerging single-layer materials.

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Metadata

Authors
M, T., & Late, D. J.
Venue
ACS Applied Materials & Interfaces
Published
2014-01-06
Volume
6
Issue
2
Pages
1158-1163
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2411435250
Cited by
211
References
1
FWCI
9.62
Type
journal article
Language
en
Open access
closed

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