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Graphene Oxide–MnFe2O4 Magnetic Nanohybrids for Efficient Removal of Lead and Arsenic from Water
Abstract
We show that the hybrids of single-layer graphene oxide with manganese ferrite magnetic nanoparticles have the best adsorption properties for efficient removal of Pb(II), As(III), and As(V) from contaminated water. The nanohybrids prepared by coprecipitation technique were characterized using atomic force and scanning electron microscopies, Fourier transformed infrared spectroscopy, Raman spectroscopy, X-ray diffraction, and surface area measurements. Magnetic character of the nanohybrids was ascertained by a vibrating sample magnetometer. Batch experiments were carried out to quantify the adsorption kinetics and adsorption capacities of the nanohybrids and compared with the bare nanoparticles of MnFe2O4. The adsorption data from our experiments fit the Langmuir isotherm, yielding the maximum adsorption capacity higher than the reported values so far. Temperature-dependent adsorption studies have been done to estimate the free energy and enthalpy of adsorption. Reusability, ease of magnetic separation, high removal efficiency, high surface area, and fast kinetics make these nanohybrids very attractive candidates for low-cost adsorbents for the effective coremoval of heavy metals from contaminated water.
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Citations
Cites
Improved Synthesis of Graphene Oxide
Marcano, D. C., Kosynkin, D. V., Berlin, J. M., Sinitskii, A., Sun, Z., Slesarev, A., Alemany, L. B., Lu, W., & Tour, J. M. (2010) · ACS Nano · doi:10.1021/nn1006368 · Cited by 11,989
Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application
Lu, A., Salabas, E. L., & Schüth, F. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200602866 · Cited by 6,777
Nanoscale iron particles for environmental remediation: An overview
Zhang, W.-X. (2003) · Journal of Nanoparticle Research · doi:10.1023/a:1025520116015 · Cited by 2,003
Water-Dispersible Magnetite-Reduced Graphene Oxide Composites for Arsenic Removal
Chandra, V., Park, J., Chun, Y., Lee, J. W., Hwang, I.-C., & Kim, K. S. (2010) · ACS Nano · doi:10.1021/nn1008897 · Cited by 1,997
New Generation Adsorbents for Water Treatment
Ali, I. (2012) · Chemical Reviews · doi:10.1021/cr300133d · Cited by 1,758
Biomedical Applications of Graphene and Graphene Oxide
Chung, C., Kim, Y.-K., Shin, D., Ryoo, S.-R., Hong, B. H., & Min, D.-H. (2013) · Accounts of Chemical Research · doi:10.1021/ar300159f · Cited by 1,696
Worldwide Occurrences of Arsenic in Ground Water
Nordstrom, D. K. (2002) · Science · doi:10.1126/science.1072375 · Cited by 1,622
Arsenic poisoning of Bangladesh groundwater
Nickson, R., McArthur, J., Burgess, W., Ahmed, K. M., Ravenscroft, P., & Rahmanñ, M. (1998) · Nature · doi:10.1038/26387 · Cited by 1,476
Low-Field Magnetic Separation of Monodisperse Fe 3 O 4 Nanocrystals
Yavuz, C. T., Mayo, J. T., Yu, W. W., Prakash, A., Falkner, J. C., Yean, S., Cong, L., Shipley, H. J., Kan, A., Tomson, M., et al. (2006) · Science · doi:10.1126/science.1131475 · Cited by 1,250
Aquatic arsenic: Toxicity, speciation, transformations, and remediation
Sharma, V. K., & Sohn, M. (2009) · Environment International · doi:10.1016/j.envint.2009.01.005 · Cited by 1,119
Superparamagnetic graphene oxide–Fe3O4 nanoparticles hybrid for controlled targeted drug carriers
Yang, X., Zhang, X., Ma, Y., Huang, Y., Wang, Y., & Chen, Y. (2009) · Journal of Materials Chemistry · doi:10.1039/b821416f · Cited by 1,046
Li, Y.-H., Ding, J., Luan, Z., Di, Z., Zhu, Y., Xu, C., Wu, D., & Wei, B. (2003) · Carbon · doi:10.1016/s0008-6223(03)00392-0 · Cited by 965
Adsorption Behavior of EDTA-Graphene Oxide for Pb (II) Removal
Madadrang, C. J., Kim, H. Y., Gao, G., Wang, N., Zhu, J., Feng, H., Gorring, M., Kasner, M. L., & Hou, S. (2012) · ACS Applied Materials & Interfaces · doi:10.1021/am201645g · Cited by 844
Adsorptive remediation of environmental pollutants using novel graphene-based nanomaterials
Wang, S., Sun, H., Ang, H. M., & Tadé, M. O. (2013) · Chemical Engineering Journal · doi:10.1016/j.cej.2013.04.070 · Cited by 729
Arsenic(III) Oxidation and Arsenic(V) Adsorption Reactions on Synthetic Birnessite
Manning, B. A., Fendorf, S. E., Bostick, B., & Suarez, D. L. (2002) · Environmental Science & Technology · doi:10.1021/es0110170 · Cited by 644
Preparation and evaluation of a novel Fe–Mn binary oxide adsorbent for effective arsenite removal
Zhang, G., Qu, J., Liu, H., Liu, R., & Wu, R. (2007) · Water Research · doi:10.1016/j.watres.2007.02.009 · Cited by 612
Folding/aggregation of graphene oxide and its application in Cu2+ removal
Yang, S.-T., Chang, Y., Wang, H., Liu, G., Chen, S., Wang, Y., Liu, Y., & Cao, A. (2010) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2010.07.042 · Cited by 599
Removal of Pb(ii) ions from aqueous solutions on few-layered graphene oxide nanosheets
Zhao, G., Ren, X., Gao, X., Tan, X., Li, J., Chen, C., Huang, Y., & Wang, X. (2011) · Dalton Transactions · doi:10.1039/c1dt11005e · Cited by 563
Zhang, S., Niu, H., Cai, Y., Zhao, X., & Shi, Y. (2010) · Chemical Engineering Journal · doi:10.1016/j.cej.2010.02.013 · Cited by 533
Fan, L., Luo, C., Sun, M., Li, X., & Qiu, H. (2013) · Colloids and Surfaces B: Biointerfaces · doi:10.1016/j.colsurfb.2012.11.006 · Cited by 474
Adsorption of Lead(II) Ions from Aqueous Solution on Low-Temperature Exfoliated Graphene Nanosheets
Huang, Z.-H., Zheng, X., Lv, W., Wang, M., Yang, Q.-H., & Kang, F. (2011) · Langmuir · doi:10.1021/la200606r · Cited by 462
Effect of magnetite particle size on adsorption and desorption of arsenite and arsenate
Yean, S., Cong, L., Yavuz, C. T., Mayo, J. T., Yu, W. W., Kan, A. T., Colvin, V. L., & Tomson, M. B. (2005) · Journal of Materials Research · doi:10.1557/jmr.2005.0403 · Cited by 431
Pseudo-second-order model for lead ion sorption from aqueous solutions onto palm kernel fiber
HO, Y., & OFOMAJA, A. (2006) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2005.08.020 · Cited by 405
Simple room-temperature preparation of high-yield large-area graphene oxide
Huang, N. M. (2011) · International Journal of Nanomedicine · doi:10.2147/ijn.s26812 · Cited by 399
Applications of surfactant-modified zeolites to environmental remediation
Bowman, R. S. (2003) · Microporous and Mesoporous Materials · doi:10.1016/s1387-1811(03)00354-8 · Cited by 359
Functionalized graphene sheets for arsenic removal and desalination of sea water
Mishra, A. K., & Ramaprabhu, S. (2011) · Desalination · doi:10.1016/j.desal.2011.01.038 · Cited by 351
Oxidation of arsenate(III) with manganese oxides in water treatment
Driehaus, W., Seith, R., & Jekel, M. (1995) · Water Research · doi:10.1016/0043-1354(94)e0089-o · Cited by 346
Graphene oxide/ferric hydroxide composites for efficient arsenate removal from drinking water
Zhang, K., Dwivedi, V., Chi, C., & Wu, J. (2010) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2010.06.010 · Cited by 344
Arsenic(III) Oxidation by Birnessite and Precipitation of Manganese(II) Arsenate
Tournassat, C., Charlet, L., Bosbach, D., & Manceau, A. (2002) · Environmental Science & Technology · doi:10.1021/es0109500 · Cited by 333
Fast Removal and Recovery of Cr(VI) Using Surface-Modified Jacobsite (MnFe2O4) Nanoparticles
Hu, J., Lo, & Chen, G. (2005) · Langmuir · doi:10.1021/la051076h · Cited by 329
A Critique of Diffuse Double Layer Models Applied to Colloid and Surface Chemistry
McBride, M. B. (1997) · Clays and Clay Minerals · doi:10.1346/ccmn.1997.0450412 · Cited by 326
Oscarson, D. W., Huang, P. M., Defosse, C., & Herbillon, A. (1981) · Nature · doi:10.1038/291050a0 · Cited by 324
Kosa, S. A., Al-Zhrani, G., & Abdel Salam, M. (2012) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.11.044 · Cited by 322
Sorption of lead ions on diatomite and manganese oxides modified diatomite
Al-Degs, Y. (2001) · Water Research · doi:10.1016/s0043-1354(01)00071-9 · Cited by 322
Nesbitt, H. W., Canning, G. W., & Bancroft, G. M. (1998) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(98)00146-x · Cited by 299
Zhang, N., Qiu, H., Si, Y., Wang, W., & Gao, J. (2011) · Carbon · doi:10.1016/j.carbon.2010.10.024 · Cited by 289
A “Sense and Shoot” Approach for Photocatalytic Degradation of Organic Contaminants in Water
Kamat, P. V., Huehn, R., & Nicolaescu, R. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp013602t · Cited by 284
Removal of lead from water by amino modified multi-walled carbon nanotubes
Vuković, G. D., Marinković, A. D., Škapin, S. D., Ristić, M. Đ., Aleksić, R., Perić-Grujić, A. A., & Uskoković, P. S. (2011) · Chemical Engineering Journal · doi:10.1016/j.cej.2011.08.036 · Cited by 272
Synthesis of Fe nanoparticles@graphene composites for environmental applications
Guo, J., Wang, R., Tjiu, W. W., Pan, J., & Liu, T. (2012) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2012.04.065 · Cited by 261
Yu, X.-Y., Luo, T., Zhang, Y.-X., Jia, Y., Zhu, B.-J., Fu, X.-C., Liu, J.-H., & Huang, X.-J. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am2004202 · Cited by 241
Chiu, V. Q., & Hering, J. G. (2000) · Environmental Science & Technology · doi:10.1021/es990788p · Cited by 217
Ngah, W. S. W., & Fatinathan, S. (2010) · Journal of Environmental Sciences · doi:10.1016/s1001-0742(09)60113-3 · Cited by 211
Adsorption of Pb(II) and Cu(II) from aqueous solution on magnetic porous ferrospinel MnFe2O4
Ren, Y., Li, N., Feng, J., Luan, T., Wen, Q., Li, Z., & Zhang, M. (2011) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2011.10.022 · Cited by 205
Efficient removal of arsenate by versatile magnetic graphene oxide composites
Sheng, G., Li, Y., Yang, X., Ren, X., Yang, S., Hu, J., & Wang, X. (2012) · RSC Advances · doi:10.1039/c2ra21623j · Cited by 194
Removal of As(III) and As(V) from water using a natural Fe and Mn enriched sample
Deschamps, E., Ciminelli, V. S. T., & Höll, W. H. (2005) · Water Research · doi:10.1016/j.watres.2005.10.007 · Cited by 190
Mishra, A. K., & Ramaprabhu, S. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp911631w · Cited by 177
Sim, L. C., Leong, K. H., Ibrahim, S., & Saravanan, P. (2014) · Journal of Materials Chemistry A · doi:10.1039/c3ta14857b · Cited by 176
Removal of Arsenic from Ground Water by Manganese Dioxide–Coated Sand
Bajpai, S., & Chaudhuri, M. (1999) · Journal of Environmental Engineering · doi:10.1061/(asce)0733-9372(1999)125:8(782 · Cited by 174
As(V) retention and As(III) simultaneous oxidation and removal on a MnO2-loaded polystyrene resin
Lenoble, V., Laclautre, C., Serpaud, B., Deluchat, V., & Bollinger, J.-C. (2004) · Science of The Total Environment · doi:10.1016/j.scitotenv.2003.12.012 · Cited by 174
Sarkar, S., Blaney, L. M., Gupta, A., Ghosh, D., & SenGupta, A. K. (2008) · Environmental Science & Technology · doi:10.1021/es702556t · Cited by 167
MnFe2O4–graphene nanocomposites with enhanced performances as anode materials for Li-ion batteries
Xiao, Y., Zai, J., Tao, L., Li, B., Han, Q., Yu, C., & Qian, X. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp50220a · Cited by 135
Arsenic: Environmental Chemistry, Health Threats and Waste Treatment
(2009) · doi:10.1002/9780470741122 · Cited by 125
Malik, D. J., Стрелко, В. В., Streat, M., & Puziy, A. M. (2002) · Water Research · doi:10.1016/s0043-1354(01)00348-7 · Cited by 124
Mahl, D., Diendorf, J., Ristig, S., Greulich, C., Li, Z., Farle, M., Köller, M., & Epple, M. (2012) · Journal of Nanoparticle Research · doi:10.1007/s11051-012-1153-5 · Cited by 112
Sverjensky, D. A., & Fukushi, K. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.05.012 · Cited by 112
Adsorption of graphene oxide/chitosan porous materials for metal ions
He, Y. Q., Zhang, N. N., & Wang, X. (2011) · Chinese Chemical Letters · doi:10.1016/j.cclet.2010.12.049 · Cited by 111
Ma, Z., Zhao, D., Chang, Y., et al. (2013) · Dalton Transactions · doi:10.1039/c3dt51310f · Cited by 77
Pan, B., Pan, B., Chen, X., Zhang, W., Zhang, X., Zhang, Q., Zhang, Q., & Chen, J. (2006) · Water Research · doi:10.1016/j.watres.2006.05.028 · Cited by 59
Upadhyay, R. V., Davies, K. J., Wells, S., & Charles, S. W. (1994) · Journal of Magnetism and Magnetic Materials · doi:10.1016/0304-8853(94)90320-4 · Cited by 57
Islam, M. R., Joung, D., & Khondaker, S. I. (2011) · New Journal of Physics · doi:10.1088/1367-2630/13/3/035021 · Cited by 37
Bellusci, M., Aliotta, C. F., Fiorani, D., Barbera, A. L., Padella, F., Peddis, D., Pilloni, M., & Secci, D. (2012) · Journal of Nanoparticle Research · doi:10.1007/s11051-012-0904-7 · Cited by 30
Mishra, A. K., & Ramaprabhu, S. (2011) · Journal of Experimental Nanoscience · doi:10.1080/17458080.2010.509872 · Cited by 15
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Yang, X., Wan, Y., Zheng, Y., He, F., Yu, Z., Huang, J., Wang, H., Ok, Y. S., Jiang, Y., & Gao, B. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.02.119 · Cited by 1,527
Role of nanomaterials in water treatment applications: A review
Santhosh, C., Velmurugan, V., Jacob, G., Jeong, S. K., Grace, A. N., & Bhatnagar, A. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.08.053 · Cited by 1,256
Ahmed, S. F., Mofijur, M., Nuzhat, S., Chowdhury, A. T., Rafa, N., Uddin, M. A., Inayat, A., Mahlia, T. M. I., Ong, H. C., Chia, W. Y., et al. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2021.125912 · Cited by 965
Xu, J., Cao, Z., Zhang, Y., Yuan, Z., Lou, Z., Xu, X., & Wang, X. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2017.12.061 · Cited by 786
Metadata
- Authors
- Kumar, S., Nair, R. R., Pillai, P. B., Gupta, S. N., Iyengar, M. A. R., & Sood, A. K.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-01
- Volume
- 6
- Issue
- 20
- Pages
- 17426-17436
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2065723967
- Cited by
- 573
- References
- 62
- FWCI
- 23.54
- Type
- journal article
- Language
- en
- Open access
- closed
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