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Surface Modification of Aramid Fibers by Bio-Inspired Poly(dopamine) and Epoxy Functionalized Silane Grafting

Sa, Rina, Yan, Yan, Wei, Zhenhai, Zhang, Liqun, Wang, Wencai, Tian, Ming·2014·ACS Applied Materials & Interfaces

Abstract

A novel biomimetic surface modification method for meta-aramid (MPIA) fibers and the improvement on adhesion with rubber matrix was demonstrated. Inspired by the composition of adhesive proteins in mussels, we used dopamine (DOPA) self-polymerization to form thin, surface-adherent poly(dopamine) (PDA) films onto the surface of MPIA fibers simply by immersing MPIA fibers in a dopamine solution at room temperature. An epoxy functionalized silane (KH560) grafting was then carried out on the surface of the poly(dopamine)-coated MPIA, either by a "one-step" or "two-step" method, to introduce an epoxy group onto the MPIA fiber surface. The surface composition and microstructure of the modified MPIA was characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). The results indicated successful grafting of KH560 on the PDA-coated MPIA surface. A single-fiber pull-out test was applied to evaluate the adhesion of MPIA fibers with the rubber matrix. Compared with the untreated MPIA fibers, the adhesion strength between the modified MPIA fibers by "one step" method with rubber matrix has an increase of 62.5%.

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Metadata

Authors
Sa, R., Yan, Y., Wei, Z., Zhang, L., Wang, W., & Tian, M.
Venue
ACS Applied Materials & Interfaces
Published
2014-11-25
Volume
6
Issue
23
Pages
21730-21738
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2091795088
Cited by
392
References
4
FWCI
22.99
Type
journal article
Language
en
Open access
closed

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