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Cellulose Nanofibril/Reduced Graphene Oxide/Carbon Nanotube Hybrid Aerogels for Highly Flexible and All-Solid-State Supercapacitors

Zheng, Qifeng, Cai, Zhiyong, Ma, Zhenqiang, Gong, Shaoqin·2015·ACS Applied Materials & Interfaces

Abstract

A novel type of highly flexible and all-solid-state supercapacitor that uses cellulose nanofibril (CNF)/reduced graphene oxide (RGO)/carbon nanotube (CNT) hybrid aerogels as electrodes and H2SO4/poly(vinyl alcohol) (PVA) gel as the electrolyte was developed and is reported here. These flexible solid-state supercapacitors were fabricated without any binders, current collectors, or electroactive additives. Because of the porous structure of the CNF/RGO/CNT aerogel electrodes and the excellent electrolyte absorption properties of the CNFs present in the aerogel electrodes, the resulting flexible supercapacitors exhibited a high specific capacitance (i.e., 252 F g(-1) at a discharge current density of 0.5 A g(-1)) and a remarkable cycle stability (i.e., more than 99.5% of the capacitance was retained after 1000 charge-discharge cycles at a current density of 1 A g(-1)). Furthermore, the supercapacitors also showed extremely high areal capacitance, areal power density, and energy density (i.e., 216 mF cm(-2), 9.5 mW cm(-2), and 28.4 μWh cm(-2), respectively). In light of its excellent electrical performance, low cost, ease of large-scale manufacturing, and environmental friendliness, the CNF/RGO/CNT aerogel electrodes may have a promising application in the development of flexible energy-storage devices.

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Research works printed but not linked: 6

  1. Shen J., 2013, ACS Appl. Mater. Interfaces, 5, 8467, 10.1021/am4028235 · doi:10.1021/am4028235
  2. Cote L. J., 2011, Pure Appl. Chem., 83, 95, 10.1351/PAC-CON-10-10-25 · doi:10.1351/pac-con-10-10-25
  3. Adsul M. G., 2011, J. Mater. Chem., 21, 2054, 10.1039/c0jm03186k · doi:10.1039/c0jm03186k
  4. Wei H. G., 2013, J. Electrochem. Soc., 160, G3038, 10.1149/2.006307jes · doi:10.1149/2.006307jes
  5. Chandrasekaran R., 2008, J. Solid State Electrochem., 12, 1349, 10.1007/s10008-008-0559-6 · doi:10.1007/s10008-008-0559-6
  6. Ganesh B., 2008, Ionics, 14, 339, 10.1007/s11581-008-0230-3 · doi:10.1007/s11581-008-0230-3

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Metadata

Authors
Zheng, Q., Cai, Z., Ma, Z., & Gong, S.
Venue
ACS Applied Materials & Interfaces
Published
2015-01-27
Volume
7
Issue
5
Pages
3263-3271
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2090340376
Cited by
417
References
57
FWCI
13.13
Type
journal article
Language
en
Open access
closed
Funders
  • University of Wisconsin-Madison
  • Forest Products Laboratory

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CoChat. (2026). Citation check: Cellulose Nanofibril/Reduced Graphene Oxide/Carbon Nanotube Hybrid Aerogels for Highly Flexible and All-Solid-State Supercapacitors. https://app.cochat.ai/papers/10.1021/am507999s
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Zheng, Q., Cai, Z., Ma, Z., & Gong, S. (2015). Cellulose Nanofibril/Reduced Graphene Oxide/Carbon Nanotube Hybrid Aerogels for Highly Flexible and All-Solid-State Supercapacitors. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am507999s

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