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Photocatalytic Activity for Hydrogen Evolution of Electrospun TiO2 Nanofibers

Chuangchote, Surawut, Jitputti, Jaturong, Sagawa, Takashi, Yoshikawa, Susumu·2009·ACS Applied Materials & Interfaces

Abstract

We report herein a simple procedure for the fabrication of TiO2 nanofibers by the combination of electrospinning and sol-gel techniques by using poly(vinylpyrrolidone) (PVP), titanium(IV) butoxide, and acetylacetone in methanol as a spinning solution. TiO2 nanofibers (260-355 nm in diameter), with a bundle of nanofibrils (20-25 nm in diameters) aligned in the fiber direction, or particle-linked structures were obtained from the calcination of as-spun TiO2/PVP composite fibers at temperatures ranging from 300 to 700 degrees C. These nanofibers were utilized as photocatalysts for hydrogen evolution. The nanofiber photocatalyst calcined at 450 degrees C showed the highest activity among the TiO2 nanofibers tested such as ones prepared by the hydrothermal method and anatase nanoparticles (Ishihara ST-01). These results indicate that one-dimensional electrospun nanofibers with highly aligned bundled nanofibrils are beneficial for enhancement of the crystallinity, large surface area, and higher photocatalytic activity.

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Metadata

Authors
Chuangchote, S., Jitputti, J., Sagawa, T., & Yoshikawa, S.
Venue
ACS Applied Materials & Interfaces
Published
2009-04-21
Volume
1
Issue
5
Pages
1140-1143
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2090909960
Cited by
242
References
0
FWCI
5.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Photocatalytic Activity for Hydrogen Evolution of Electrospun TiO2 Nanofibers. https://app.cochat.ai/papers/10.1021/am9001474
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Chuangchote, S., Jitputti, J., Sagawa, T., & Yoshikawa, S. (2009). Photocatalytic Activity for Hydrogen Evolution of Electrospun TiO2 Nanofibers. ACS Applied Materials & Interfaces. https://doi.org/10.1021/am9001474

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