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Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks
Abstract
Secondary building units (SBUs) are molecular complexes and cluster entities in which ligand coordination modes and metal coordination environments can be utilized in the transformation of these fragments into extended porous networks using polytopic linkers (1,4-benzenedicarboxylate, 1,3,5,7-adamantanetetracarboxylate, etc.). Consideration of the geometric and chemical attributes of the SBUs and linkers leads to prediction of the framework topology, and in turn to the design and synthesis of a new class of porous materials with robust structures and high porosity.
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Citations
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Engineering coordination polymers towards applications
Janiak, C. (2003) · Dalton Transactions · doi:10.1039/b305705b · Cited by 3,374
Perry IV, J. J., Perman, J. A., & Zaworotko, M. J. (2009) · Chemical Society Reviews · doi:10.1039/b807086p · Cited by 1,768
The hydrothermal synthesis of zeolites: Precursors, intermediates and reaction mechanism
Cundy, C. S., & Cox, P. A. (2005) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2005.02.016 · Cited by 1,590
Metadata
- Authors
- Eddaoudi, M., Moler, D. B., Li, H., Chen, B., Reineke, T. M., O'Keeffe, M., & Yaghi, O. M.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-02-17
- Volume
- 34
- Issue
- 4
- Pages
- 319-330
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2164043498
- Cited by
- 5,180
- References
- 0
- FWCI
- 146.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks. https://app.cochat.ai/papers/10.1021/ar000034b
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- Eddaoudi, M., Moler, D. B., Li, H., Chen, B., Reineke, T. M., O'Keeffe, M., & Yaghi, O. M. (2001). Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks. Accounts of Chemical Research. https://doi.org/10.1021/ar000034b
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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