The DOI matches its Crossref record.
Green, Catalytic Oxidations of Alcohols
Abstract
Three methods are described, in the context of the guiding principles of green chemistry, for the catalytic oxidation of alcohols. The first employs a recyclable oligomeric TEMPO catalyst (PIPO) and sodium hypochlorite as the oxidant in a bromide-free and chlorinated hydrocarbon solvent-free system. The second involves a ruthenium/TEMPO catalyst and oxygen as the oxidant. The third consists of a recyclable water-soluble palladium-diamine complex in conjunction with air as the oxidant in an aqueous biphasic system. The mechanisms of the ruthenium/TEMPO- and palladium-catalyzed oxidations are discussed, and the mechanism of the former is compared with that of the analogous copper/TEMPO catalyst.
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Metadata
- Authors
- Sheldon, R. A., Arends, I. W. C. E., ten Brink, G.-J., & Dijksman, A.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-06-20
- Volume
- 35
- Issue
- 9
- Pages
- 774-781
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2033020343
- Cited by
- 1,171
- References
- 0
- FWCI
- 22.24
- Type
- journal article
- Language
- en
- Open access
- closed
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