The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach
Abstract
Oxidation reactions are of fundamental importance in nature, and are key transformations in organic synthesis. The development of new processes that employ transition metals as substrate‐selective catalysts and stoichiometric environmentally friendly oxidants, such as molecular oxygen or hydrogen peroxide, is one of the most important goals in oxidation chemistry. Direct oxidation of the catalyst by molecular oxygen or hydrogen peroxide is often kinetically unfavored. The use of coupled catalytic systems with electron‐transfer mediators (ETMs) usually facilitates the procedures by transporting the electrons from the catalyst to the oxidant along a low‐energy pathway, thereby increasing the efficiency of the oxidation and thus complementing the direct oxidation reactions. As a result of the similarities with biological systems, this can be dubbed a biomimetic approach.
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Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
C−H Bond Activation and Organometallic Intermediates on Isolated Metal Centers on Oxide Surfaces
Coperet, C. (2010) · Chemical Reviews · doi:10.1021/cr900122p · Cited by 434
Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β‐Hydroxysulfones
Lu, Q., Zhang, J., Wei, F., Qi, Y., Wang, H., Liu, Z., & Lei, A. (2013) · Angewandte Chemie · doi:10.1002/ange.201301634 · Cited by 331
Nitroxide-catalyzed transition-metal-free aerobic oxidation processes
Wertz, S., & Studer, A. (2013) · Green Chemistry · doi:10.1039/c3gc41459k · Cited by 323
Huynh, M. T., Anson, C. W., Cavell, A. C., Stahl, S. S., & Hammes-Schiffer, S. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b05797 · Cited by 308
Metadata
- Authors
- Piera, J., & Bäckvall, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-04-21
- Volume
- 47
- Issue
- 19
- Pages
- 3506-3523
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2146242081
- Cited by
- 889
- References
- 34
- FWCI
- 27.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Piera, J., & Bäckvall, J. (2008). Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200700604
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