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Cited by 403

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Reversible Binding of Oxygen to Aromatic Compounds

Aubry, Jean-Marie, Pierlot, Christel, Rigaudy, Jean, Schmidt, Reinhard·2003·Accounts of Chemical Research

Abstract

Many polycyclic aromatic hydrocarbons are able to trap singlet oxygen (1)O(2). Some of the endoperoxides, thus obtained, exhibit the exceptional feature of releasing oxygen, frequently in the excited singlet state, under heating or UV irradiation. In this Account, we provide a short summary of the present knowledge on these endoperoxides: preparation and thermal and photolytic decomposition, with a special emphasis on the structural requirements to favor cycloreversion. The profitable use of this property in the development of highly reversible photochromic systems and of specific sources or traps of (1)O(2) in aqueous media is also described.

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Metadata

Authors
Aubry, J.-M., Pierlot, C., Rigaudy, J., & Schmidt, R.
Venue
Accounts of Chemical Research
Published
2003-07-09
Volume
36
Issue
9
Pages
668-675
ISSN
  • 0001-4842 (ISSN-L)
  • 1520-4898
OpenAlex
W2172167168
Cited by
403
References
1
FWCI
6.49
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Reversible Binding of Oxygen to Aromatic Compounds. https://app.cochat.ai/papers/10.1021/ar010086g
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Aubry, J.-M., Pierlot, C., Rigaudy, J., & Schmidt, R. (2003). Reversible Binding of Oxygen to Aromatic Compounds. Accounts of Chemical Research. https://doi.org/10.1021/ar010086g

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