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Rich Structure Chemistry in the Aluminophosphate Family
Abstract
This Account describes a family of aluminophosphates ranging from neutral open-frameworks to anionic frameworks with fascinating structural architectures. In contrast to aluminosilicate zeolites, these aluminophosphates exhibit wealthy structural features, including extra-large micropores, mixed bonding, different structural dimensionalities, rich compositional diversities, and various stacking sequences of their 2-D sheets. The low-dimensional networks, acting as building units, can be assembled to 3-D open-frameworks via transition metal cations through a building-up process. New stoichiometries and hypothetical structural topologies can be predicted and enumerated. Computational and combinatorial approaches will greatly help to access the range of the diverse structures.
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Cited by
Towards the Rational Design of Efficient Organic Structure‐Directing Agents for Zeolite Synthesis
Moliner, M., Rey, F., & Corma, A. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201304713 · Cited by 371
Introduction to the Zeolite Structure-Directing Phenomenon by Organic Species: General Aspects
Gómez-Hortigüela, L., & Camblor, M. Á. (2017) · Structure and Bonding · doi:10.1007/430_2017_8 · Cited by 35
Metadata
- Authors
- Yu, J., & Xu, R.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-03-27
- Volume
- 36
- Issue
- 7
- Pages
- 481-490
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2111396745
- Cited by
- 338
- References
- 0
- FWCI
- 17.02
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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