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Enamine Catalysis Is a Powerful Strategy for the Catalytic Generation and Use of Carbanion Equivalents
Abstract
The chemistry of preformed enamines, especially their use as enolate equivalents, has been a well-investigated area of research since the early 1950s. However, enamine catalysis, the catalysis of carbonyl transformations via enamine intermediates by using primary and secondary amines as catalysts, has only been fully appreciated as a powerful strategy for asymmetric synthesis since the beginning of this century. Contributions from this laboratory to the revitalized interest in asymmetric enamine catalysis are summarized in this Account.
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Mechanochemistry: opportunities for new and cleaner synthesis
James, S. L., Adams, C. J., Bolm, C., Braga, D., Collier, P., Friščić, T., Grepioni, F., Harris, K. D. M., Hyett, G., Jones, W., et al. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15171a · Cited by 3,056
Asymmetric Catalysis by Chiral Hydrogen‐Bond Donors
Taylor, M. S., & Jacobsen, E. N. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200503132 · Cited by 1,906
Asymmetric Aminocatalysis—Gold Rush in Organic Chemistry
Melchiorre, P., Marigo, M., Carlone, A., & Bartoli, G. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200705523 · Cited by 1,256
Kobayashi, S., Mori, Y., Fossey, J. S., & Salter, M. M. (2011) · Chemical Reviews · doi:10.1021/cr100204f · Cited by 988
When Organocatalysis Meets Transition‐Metal Catalysis
Zhong, C., & Shi, X. (2010) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201000004 · Cited by 607
Metadata
- Authors
- List, B.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-05-13
- Volume
- 37
- Issue
- 8
- Pages
- 548-557
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2118312031
- Cited by
- 765
- References
- 0
- FWCI
- 36.65
- Type
- journal article
- Language
- en
- Open access
- closed
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