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Cited by 706

The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.

Alfred Werner Revisited: The Coordination Chemistry of Anions

Bowman-James, Kristin·2005·Accounts of Chemical Research

Abstract

A series of macrocyclic receptors were designed to probe the influence of four factors, hydrogen bonding, charge, dimensionality, and topology, on anion binding. Monocyclic and bicyclic polyammonium and polyamide receptors were synthesized from either 2,2'-diaminodiethylamine derivatives (dien) or 2,2',2''-aminoethylamine (tren) building blocks, plus aromatic or heterocyclic spacers. Supramolecular complexes of these hosts with three simple anion topologies were probed: spherical (halides), trigonal planar (nitrate), and tetrahedral (sulfate). Results indicate a number of corollaries with transition-metal coordination chemistry in terms of binding concepts such as the chelate effect and dual valencies, as well as geometries for anion complexes that are strikingly similar to those observed in transition-metal coordination chemistry.

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Metadata

Authors
Bowman-James, K.
Venue
Accounts of Chemical Research
Published
2005-06-25
Volume
38
Issue
8
Pages
671-678
ISSN
  • 0001-4842 (ISSN-L)
  • 1520-4898
OpenAlex
W2132680031
Cited by
706
References
4
FWCI
32.75
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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