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Design, Chirality, and Flexibility in Nanoporous Molecule-Based Materials
Abstract
Scientific and technological interest in porous materials with molecule-sized channels and cavities has led to an intense search for controlled chemical routes to systems with specific properties. This Account details our work on directing the assembly of open-framework structures based on molecules and investigating how the response of nanoporous examples of such materials to guests differs from classical rigid porous systems. The stabilization of chiral nanoporosity by a hierarchy of interactions that both direct and maintain a helical open-framework structure exemplifies the approach.
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Metadata
- Authors
- Bradshaw, D., Claridge, J. B., Cussen, E. J., Prior, T. J., & Rosseinsky, M. J.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-01-08
- Volume
- 38
- Issue
- 4
- Pages
- 273-282
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2152932169
- Cited by
- 1,245
- References
- 15
- FWCI
- 69.74
- Type
- journal article
- Language
- en
- Open access
- closed
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