The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Pseudo-rotation in the hydrolysis of phosphate esters
Abstract
Abstract. The hydrolysis of a phosphate, phosphonate or phosphinate ester gen-eraUy takes place either through a trigonal bipyramidal hydroxyphosphorane as intermediate (with expansion of the coordination number of phosphorus from four to five) or (at least for phosphates) through a moaomeric metaphosphate as inter-mediate (with contraction of the coordination number of phosphorus from four to three). These processes parai.lel the principal mechanisms for the hydrolysis of carboxylic esters, which require either the formation of a tetrahedral interme-diate or that of an acylium cation.
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Citations
Cites
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Self-citationThe Hydrolysis of Some Cyclic Esters of Sulfuric Acid
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Cited by
Westheimer, F. H. (1987) · Science · doi:10.1126/science.2434996 · Cited by 1,711
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The Pentacovalent Phosphorus Intermediate of a Phosphoryl Transfer Reaction
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Abiotic Regioselective Phosphorylation of Adenosine with Borate in Formamide
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Metadata
- Authors
- Westheimer, F. H.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 1968-03-01
- Volume
- 1
- Issue
- 3
- Pages
- 70-78
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W1967018847
- Cited by
- 772
- References
- 12
- FWCI
- 19.08
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
