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Anion Binding Involving π-Acidic Heteroaromatic Rings
Abstract
Anions are essential species in biological systems and, particularly, in enzyme-substrate recognition. Therefore, the design and preparation of anion receptors is a topical field of supramolecular chemistry. Most host-guest systems successfully developed are based on noncovalent (ionic and hydrogen-bonded) interactions between anions and ammonium-type functionalities or Lewis acid groups. However, since the past 5 years, an alternative route toward the synthesis of efficient anion hosts has emerged, namely, the use of "anion-pi" interactions involving nitrogen-containing electron-deficient aromatic rings, as the result of several favorable theoretical investigations. In this Account, the state of the (new) art in this growing area of anion-binding research is presented and several selected examples from our work and that of other groups will be discussed.
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Metadata
- Authors
- Gamez, P., Mooibroek, T. J., Teat, S. J., & Reedijk, J.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-04-18
- Volume
- 40
- Issue
- 6
- Pages
- 435-444
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2151037107
- Cited by
- 539
- References
- 0
- FWCI
- 25.56
- Type
- journal article
- Language
- en
- Open access
- closed
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