The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Room-Temperature Ionic Liquids: Slow Dynamics, Viscosity, and the Red Edge Effect
Abstract
Ionic liquids (ILs) have recently attracted significant attention from academic and industrial sources. This is because, while their vapor pressures are negligible, many of them are liquids at room temperature and can dissolve a wide range of polar and nonpolar organic and inorganic molecules. In this Account, we discuss the progress of our laboratory in understanding the dynamics, spectroscopy, and fluid dynamics of selected imidazolium-based ILs using computational and analytical tools that we have recently developed. Our results indicate that the red edge effect, the non-Newtonian behavior, and the existence of locally heterogeneous environments on a time scale relevant to chemical and photochemical reactivity are closely linked to the viscosity and highly structured character of these liquids.
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Cites
Influence of chloride, water, and organic solvents on the physical properties of ionic liquids
Seddon, K. R., Stark, A., & Torres, M.-J. (2000) · Pure and Applied Chemistry · doi:10.1351/pac200072122275 · Cited by 2,293
Cited by
Castner, E. W., & Wishart, J. F. (2010) · The Journal of Chemical Physics · doi:10.1063/1.3373178 · Cited by 398
Zhao, W., Leroy, F., Heggen, B., Zahn, S., Kirchner, B., Balasubramanian, S., & Müller-Plathe, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja906337p · Cited by 313
Timilsina, A., Adhikari, K., Yadav, A. K., Joshi, P., Ramena, G., & Bohara, K. (2023) · Science of The Total Environment · doi:10.1016/j.scitotenv.2023.164999 · Cited by 104
Metadata
- Authors
- Hu, Z., & Margulis, C. J.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-07-28
- Volume
- 40
- Issue
- 11
- Pages
- 1097-1105
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2057105206
- Cited by
- 205
- References
- 1
- FWCI
- 7.13
- Type
- journal article
- Language
- en
- Open access
- closed
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