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Cited by 205

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Room-Temperature Ionic Liquids: Slow Dynamics, Viscosity, and the Red Edge Effect

Hu, Zhonghan, Margulis, Claudio J.·2007·Accounts of Chemical Research

Abstract

Ionic liquids (ILs) have recently attracted significant attention from academic and industrial sources. This is because, while their vapor pressures are negligible, many of them are liquids at room temperature and can dissolve a wide range of polar and nonpolar organic and inorganic molecules. In this Account, we discuss the progress of our laboratory in understanding the dynamics, spectroscopy, and fluid dynamics of selected imidazolium-based ILs using computational and analytical tools that we have recently developed. Our results indicate that the red edge effect, the non-Newtonian behavior, and the existence of locally heterogeneous environments on a time scale relevant to chemical and photochemical reactivity are closely linked to the viscosity and highly structured character of these liquids.

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Metadata

Authors
Hu, Z., & Margulis, C. J.
Venue
Accounts of Chemical Research
Published
2007-07-28
Volume
40
Issue
11
Pages
1097-1105
ISSN
  • 0001-4842 (ISSN-L)
  • 1520-4898
OpenAlex
W2057105206
Cited by
205
References
1
FWCI
7.13
Type
journal article
Language
en
Open access
closed

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