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Oligothienylenevinylenes as a New Class of Multinanometer Linear π-Conjugated Systems for Micro- and Nanoelectronics
Abstract
This Account deals with the synthesis and characterization of monodisperse soluble oligothienylenevinylenes with chain lengths up to 100 A. The chain length dependence of the electronic and electrochemical properties both in solution and in the solid state are analyzed and discussed in the context of the potential use of oligothienylenevinylenes as molecular wires. Problems related to interchain interactions are illustrated by the analysis of the effects of structure on the reversible dimerization of cation radicals and by the synthesis of new series of end-substituted oligomers.
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Cited by
Roquet, S., Cravino, A., Leriche, P., Alévêque, O., Frère, P., & Roncali, J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058178e · Cited by 787
Self-citationMolecular Engineering of the Band Gap of π‐Conjugated Systems: Facing Technological Applications
Roncali, J. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200700345 · Cited by 722
Self-citationLinkers for anchoring sensitizers to semiconductor nanoparticles
Galoppini, E. (2004) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.03.016 · Cited by 417
Arrechea, S., Aljarilla, A., de la Cruz, P., Palomares, E., Sharma, G. D., & Langa, F. (2016) · Nanoscale · doi:10.1039/c6nr06374h · Cited by 27
Arrechea, S., Aljarilla, A., de la Cruz, P., Singh, M. K., Sharma, G. D., & Langa, F. (2017) · Journal of Materials Chemistry C · doi:10.1039/c7tc00812k · Cited by 21
Metadata
- Authors
- Roncali, J.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-02-02
- Volume
- 33
- Issue
- 3
- Pages
- 147-156
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2001948045
- Cited by
- 216
- References
- 0
- FWCI
- 12.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Roncali, J. (2000). Oligothienylenevinylenes as a New Class of Multinanometer Linear π-Conjugated Systems for Micro- and Nanoelectronics. Accounts of Chemical Research. https://doi.org/10.1021/ar990023m
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