Efficiency improvement using bis(trifluoromethane) sulfonamide lithium salt as a chemical additive in porphyrin based organic solar cells
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Two new conjugated acceptor-π-donor-π-acceptor (A-π-D-π-A) porphyrins have been synthesised using 3-ethylrhodanine (1a) or dicyanovinylene (1b) groups as acceptor units. Their optical and electrochemical properties made these materials excellent electron donors along with PC 71 BM as the acceptor for solution-processed bulk heterojunction organic solar cells. The devices based on 1a:PC 71 BM (1 : 2) and 1b:PC 71 BM (1 : 2) processed with CB showed low power conversion efficiencies (PCE) of 2.30% and 2.80%, respectively. Nonetheless, after processing the active layer using a mixture of 3 vol% of a pyridine additive in THF, the PCE was enhanced up to 5.14% and 6.06% for 1a:PC 71 BM and 1b:PC 71 BM, respectively. Moreover, when we used LiTFSI as the chemical additive in pyridine/CB-processed 1b:PC 71 BM an excellent PCE of 7.63% was recorded. The effects over the film morphology and the device characteristics (J sc , V oc and FF) due to the introduction of LiTFSI are discussed.
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Overall PCEs of 5.14% and 6.06% were obtained from optimized devices (pyridine additive in chloroform) based on E13 and E14, respectively.
“Overall PCEs of 5.14% and 6.06% could be obtained from optimized devices (pyridine additive in chloroform) based on E13 and E14 , respectively.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [102]
When Li-TFSI was used as the chemical additive, the E14:PC71BM based device showed a PCE of 7.63%.
“When Li-TFSI was used as the chemical additive, the E14 :PC71BM based device showed a PCE of 7.63%.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [102]
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Forstenhäusler, M., López‐Guerra, E. A., & Solares, S. D. J. (2021) · Facta Universitatis Series Mechanical Engineering · doi:10.22190/fume200920009f · Cited by 1 · see citing works
p ‐Type Molecular Photovoltaic Materials
Yue, Q., & Zhu, X. (2022) · Wiley eBooks · doi:10.1002/9783527833658.ch2
- Authors
- Arrechea, S., Aljarilla, A., de la Cruz, P., Palomares, E., Sharma, G. D., & Langa, F.
- Affiliations
- Universidad de San Carlos de Guatemala (GT)
- University of Castilla-La Mancha (ES)
- Institució Catalana de Recerca i Estudis Avançats (ES)
- LNM Institute of Information Technology (IN)
- Corresponding author
- Palomares, Emilio
- Sharma, Ganesh D.
- Langa, Fernando
- Venue
- Nanoscale
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 8
- Issue
- 41
- Pages
- 17953-17962
- ISSN
- 2040-3364 (ISSN-L)
- 2040-3372
- OpenAlex
- W2522229346
- Cited by
- 27
- References
- 74
- Citations by year
- 2025: 1 · 2024: 1 · 2023: 1 · 2022: 2 · 2021: 2 · 2020: 5 · 2019: 5 · 2018: 3 · 2017: 7
- FWCI
- 2.31
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- other-oa
- Locations
- Nanoscale (publishedVersion)
- PubMed (publishedVersion)
- LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (submittedVersion, other-oa)
- RUIdeRA - Institutional University Repository (University of Castilla-La Mancha) (submittedVersion, other-oa)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Health Sciences › Medicine › Pulmonary and Respiratory Medicine › Photodynamic Therapy Research Studies
- Keywords
- organic solar cells, bulk heterojunction, pyridine additive, PC71BM, power conversion efficiency, film morphology, electron donor materials
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