The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Theoretical Perspectives on Proton-Coupled Electron Transfer Reactions
Abstract
This Account presents a theoretical formulation for proton-coupled electron transfer reactions. The active electrons and transferring protons are treated quantum mechanically, and the free energy surfaces are obtained as functions of collective solvent coordinates corresponding to the proton and electron transfer reactions. Rate expressions have been derived in the relevant limits, and methodology for including the dynamical effects of the solvent and protein has been developed. This theoretical framework allows predictions of rates, mechanisms, and kinetic isotope effects for proton-coupled electron transfer reactions.
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Citations
Cites
Reaction-rate theory: fifty years after Kramers
Hänggi, P., Talkner, P., & Borkovec, M. (1990) · Reviews of Modern Physics · doi:10.1103/revmodphys.62.251 · Cited by 6,154
Tomasi, J., & Persico, M. (1994) · Chemical Reviews · doi:10.1021/cr00031a013 · Cited by 5,503
Chemical and Electrochemical Electron-Transfer Theory
Marcus, R. A. (1964) · Annual Review of Physical Chemistry · doi:10.1146/annurev.pc.15.100164.001103 · Cited by 4,408
Contemporary Issues in Electron Transfer Research
Barbara, P. F., Meyer, T. J., & Ratner, M. A. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9605663 · Cited by 1,558
Computer Modeling of Chemical Reactions in Enzymes and Solutions
Warshel, A. (1991) · Medical Entomology and Zoology · Cited by 1,128
Oxygen activation and the conservation of energy in cell respiration
Babcock, G. T., & Wikström, M. (1992) · Nature · doi:10.1038/356301a0 · Cited by 1,125
Electron Transfer—from Isolated Molecules to Biomolecules
Bixon, M., & Jortner, J. (1999) · Advances in Chemical Physics · doi:10.1002/9780470141656.ch3 · Cited by 857
PROTON-COUPLED ELECTRON TRANSFER
Cukier, R. I., & Nocera, D. G. (1998) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.49.1.337 · Cited by 854
Photoinduced electron transfer mediated by a hydrogen-bonded interface
Turro, C., Chang, C. K., Leroi, G. E., Cukier, R. I., & Nocera, D. G. (1992) · Journal of the American Chemical Society · doi:10.1021/ja00036a081 · Cited by 247
Dynamical theory of proton tunneling transfer rates in solution: general formulation
Borgis, D., & Hynes, J. T. (1993) · Chemical Physics · doi:10.1016/0301-0104(93)85117-q · Cited by 241
Cited by
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis
Koper, M. T. M. (2011) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2010.10.004 · Cited by 1,204
The catalytic pathway of horseradish peroxidase at high resolution
Berglund, G. I., Carlsson, G. H., Smith, A. T., Szöke, H., Henriksen, A., & Hajdu, J. (2002) · Nature · doi:10.1038/417463a · Cited by 956
Theory of Coupled Electron and Proton Transfer Reactions
Hammes-Schiffer, S., & Stuchebrukhov, A. A. (2010) · Chemical Reviews · doi:10.1021/cr1001436 · Cited by 848
Self-citationLevine, R. D. (2005) · Cambridge University Press eBooks · doi:10.1017/cbo9780511614125 · Cited by 709
Proton-Coupled Electron Transfer: Moving Together and Charging Forward
Hammes-Schiffer, S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b04087 · Cited by 468
Self-citationChemistry of Personalized Solar Energy
Nocera, D. G. (2009) · Inorganic Chemistry · doi:10.1021/ic901328v · Cited by 395
Mayer, J. M., Hrovat, D. A., Thomas, J. L., & Borden, W. T. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012732c · Cited by 379
Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer
Warburton, R. E., Soudackov, A. V., & Hammes-Schiffer, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00929 · Cited by 322
Self-citationReece, S. Y., Hodgkiss, J. M., Stubbe, J., & Nocera, D. G. (2006) · Philosophical Transactions of the Royal Society B: Biological Sciences · doi:10.1098/rstb.2006.1874 · Cited by 294
Environmentally coupled hydrogen tunneling: Linking catalysis to dynamics
Knapp, M. J., & Klinman, J. P. (2002) · European Journal of Biochemistry · doi:10.1046/j.1432-1033.2002.03022.x · Cited by 281
Usharani, D., Lacy, D. C., Borovik, A. S., & Shaik, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408073m · Cited by 278
Pulsed Laser in Liquids Made Nanomaterials for Catalysis
Forsythe, R. C., Cox, C. P., Wilsey, M. K., & Müller, A. M. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01069 · Cited by 259
Metadata
- Authors
- Hammes-Schiffer, S.
- Venue
- Accounts of Chemical Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-01-18
- Volume
- 34
- Issue
- 4
- Pages
- 273-281
- ISSN
- 0001-4842 (ISSN-L)
- 1520-4898
- OpenAlex
- W2056768042
- Cited by
- 450
- References
- 24
- FWCI
- 17.53
- Type
- journal article
- Language
- en
- Open access
- closed
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