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CO2 Acceptor Gasification Process: Studies of Acceptor Properties
Abstract
The CO 2 Acceptor Gasification Process is discussed in light of the required properties of the CaO acceptor. Equilibrium data for reactions involving the CO 2 and sulfur acceptance and for sulfur rejection fit the process requirements. The kinetics of the reactions are also sufficiently rapid. Phase equilibrium data in the binary systems CaO—Ca(OH) 2 and Ca(OH) 2 —CaCO 3 show the presence of low melting eutectics, which establish operability limits for the process. Data were obtained in a continuous unit which duplicates process conditions which show adequate acceptor life. Physical strength of many acceptors is adequate, and life is limited by chemical deactivation. Contrary to earlier findings both limestones and dolomites are equally usable in the process. Melts in the Ca(OH) 2 —CaCO 3 system are used to reactivate spent acceptors.
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Cited by
Carbon capture and storage update
Boot-Handford, M. E., Abanades, J. C., Anthony, E. J., Blunt, M. J., Brandani, S., Mac Dowell, N., Fernández, J. R., Ferrari, M.-C., Gross, R., Hallett, J. P., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee42350f · Cited by 2,386
Abanades, J. C., Arias, B., Lyngfelt, A., Mattisson, T., Wiley, D. E., Li, H., Ho, M. T., Mangano, E., & Brandani, S. (2015) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2015.04.018 · Cited by 441
Dean, C. C., Blamey, J., Florin, N. H., Al-Jeboori, M. J., & Fennell, P. S. (2011) · Chemical Engineering Research and Design · doi:10.1016/j.cherd.2010.10.013 · Cited by 375
Capture of CO2 from combustion gases in a fluidized bed of CaO
Abanades, J. C., Anthony, E. J., Lu, D. Y., Salvador, C., & Alvarez, D. (2004) · AIChE Journal · doi:10.1002/aic.10132 · Cited by 373
Performance Enhancement of Calcium Oxide Sorbents for Cyclic CO2 Capture—A Review
Liu, W., An, H., Qin, C., Yin, J., Wang, G., Feng, B., & Xu, M. (2012) · Energy & Fuels · doi:10.1021/ef300220x · Cited by 320
Metadata
- Authors
- CURRAN, G. P., FINK, C. E., & GORIN, E.
- Venue
- Advances in Chemistry
- Publisher
- AMERICAN CHEMICAL SOCIETY
- Published
- 1967-06-01
- Pages
- 141-165
- ISSN
- 0065-2393 (ISSN-L)
- OpenAlex
- W268173000
- Cited by
- 171
- References
- 0
- FWCI
- 0.00
- Type
- book chapter
- Language
- en
- Open access
- closed
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- CURRAN, G. P., FINK, C. E., & GORIN, E. (1967). CO2 Acceptor Gasification Process: Studies of Acceptor Properties. Advances in Chemistry. https://doi.org/10.1021/ba-1967-0069.ch010
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