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Cited by 502

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Superior Solubility of Polysaccharides in Low Viscosity, Polar, and Halogen-Free 1,3-Dialkylimidazolium Formates

Fukaya, Yukinobu, Sugimoto, Akiko, Ohno, Hiroyuki·2006·Biomacromolecules
DOI 10.1021/bm060327d
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Abstract

We successfully prepared low viscosity, polar, and halogen-free ionic liquids as potential solvents for a wide range of polysaccharides. A series of 1,3-dialkylimidazolium formates were produced as liquids having strong hydrogen bond acceptability. These formates had significantly lower viscosity than previously reported polar ionic liquids, in particular 1-allyl-3-methylimidazolium formate (viscosity 66cP at 25 degrees C) and 1-allyl-3-ethylimidazolium formate (67cP at 25 degrees C). Because of their strong hydrogen bond ability, various polysaccharides including amylose and (scarcely soluble) cellulose were dissolved in high concentrations under mild condition.

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Metadata

Authors
Fukaya, Y., Sugimoto, A., & Ohno, H.
Venue
Biomacromolecules
Publisher
American Chemical Society (ACS)
Published
2006-11-14
Volume
7
Issue
12
Pages
3295-3297
ISSN
  • 1525-7797 (ISSN-L)
  • 1526-4602
DOI
10.1021/bm060327d
OpenAlex
W2046271296
Cited by
502
References
0
FWCI
6.01
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Superior Solubility of Polysaccharides in Low Viscosity, Polar, and Halogen-Free 1,3-Dialkylimidazolium Formates. https://app.cochat.ai/papers/10.1021/bm060327d
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Fukaya, Y., Sugimoto, A., & Ohno, H. (2006). Superior Solubility of Polysaccharides in Low Viscosity, Polar, and Halogen-Free 1,3-Dialkylimidazolium Formates. Biomacromolecules. https://doi.org/10.1021/bm060327d

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.