Cellulose dissolution with polar ionic liquids under mild conditions: required factors for anions
Abstract
A series of alkylimidazolium salts containing dimethyl phosphate, methyl methylphosphonate, or methyl phosphonate prepared by a facile, one-pot procedure were obtained as room temperature ionic liquids, which have the potential to solubilize cellulose under mild conditions. Especially, N-ethyl-N′-methylimidazolium methylphosphonate enables the preparation of 10 wt% cellulose solution by keeping it at 45 °C for 30 min with stirring and rendered soluble 2–4 wt% cellulose without pretreatments and heating.
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Cellulose dissolution is an industrially attractive application of ionic liquids due to good solubilities (5-20 wt%, depending on ionic liquid and conditions), competitive properties of regenerated cellulose, increased stability of ionic liquid cellulose solutions, and low toxicity of certain relevant ionic liquids.
“Cellulose dissolution is an industrially attractive application of ionic liquids, due to good solubilities (5-20 wt%, depending on the ionic liquid and the conditions), the competitive properties of cellulose reprecipitated from the ionic liquid solutions, 73 the increased stability of ionic liquid cellulose solutions 74 and the low toxicity of certain relevant ionic liquids (for example, [C 2 C 1”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [73]
Cites
Dissolution of Cellose with Ionic Liquids
Swatloski, R. P., Spear, S. K., Holbrey, J. D., & Rogers, R. D. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025790m · Cited by 4,735 · see citing works
Zhang, H., Wu, J. L., Zhang, J., & He, J. (2005) · Macromolecules · doi:10.1021/ma0505676 · Cited by 1,437 · see citing works
Electrochemical aspects of ionic liquids
(2005) · Choice Reviews Online · doi:10.5860/choice.43-1569 · Cited by 1,205 · see citing works
Rapid Dissolution of Cellulose in LiOH/Urea and NaOH/Urea Aqueous Solutions
Cai, J., & Zhang, L. (2005) · Macromolecular Bioscience · doi:10.1002/mabi.200400222 · Cited by 1,061 · see citing works
Solvent–solute interactions in ionic liquids
Crowhurst, L., Mawdsley, P. R., Perez‐Arlandis, J. M., Salter, P. A., & Welton, T. (2003) · Physical Chemistry Chemical Physics · doi:10.1039/b303095d · Cited by 776 · see citing works
Remsing, R. C., Swatloski, R. P., Rogers, R. D., & Moyna, G. (2006) · Chemical Communications · doi:10.1039/b600586c · Cited by 712 · see citing works
Solution studies of cellulose in lithium chloride and N,N-dimethylacetamide
McCormick, C. L., Callais, P. A., & Hutchinson, B. H. (1985) · Macromolecules · doi:10.1021/ma00154a010 · Cited by 673 · see citing works
Armstrong, D. W., He, L., & Liu, Y.-S. (1999) · Analytical Chemistry · doi:10.1021/ac990443p · Cited by 623 · see citing works
Fukaya, Y., Sugimoto, A., & Ohno, H. (2006) · Biomacromolecules · doi:10.1021/bm060327d · Cited by 504 · see citing works
Self-citationDissolution and Regeneration of Bombyx mori Silk Fibroin Using Ionic Liquids
Phillips, D. M., Drummy, L. F., Conrady, D. G., Fox, D. M., Naik, R. R., Stone, M. O., Trulove, P. C., Long, H. C. D., & Mantz, R. A. (2004) · Journal of the American Chemical Society · doi:10.1021/ja046079f · Cited by 479 · see citing works
Ionic liquids as novel solvents for the dissolution and blending of wool keratin fibers
Xie, H., Li, S., & Zhang, S. (2005) · Green Chemistry · doi:10.1039/b502547h · Cited by 395 · see citing works
High-resolution 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions
Moulthrop, J. S., Swatloski, R. P., Moyna, G., & Rogers, R. D. (2005) · Chemical Communications · doi:10.1039/b417745b · Cited by 345 · see citing works
Production of Bioactive Cellulose Films Reconstituted from Ionic Liquids
Turner, M. B., Spear, S. K., Holbrey, J. D., & Rogers, R. D. (2004) · Biomacromolecules · doi:10.1021/bm049748q · Cited by 344 · see citing works
Tetraalkylphosphonium-based ionic liquids
Sesto, R. E. D., Corley, C. A., Robertson, A. J., & Wilkes, J. S. (2004) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2004.09.060 · Cited by 280 · see citing works
Baker, S. N., Baker, G. A., & Bright, F. V. (2002) · Green Chemistry · doi:10.1039/b111285f · Cited by 235 · see citing works
Rapid, clean, and mild O-acetylation of alcohols and carbohydrates in an ionic liquid
Forsyth, S. A., MacFarlane, D. R., Thomson, R. J., & von Itzstein, M. (2002) · Chemical Communications · doi:10.1039/b200306f · Cited by 202 · see citing works
Oriented cellulose films and fibers from a mesophase system
Chanzy, H., Péguy, A., Chaunis, S., & Monzie, P. (1980) · Journal of Polymer Science Polymer Physics Edition · doi:10.1002/pol.1980.180180517 · Cited by 198 · see citing works
Kuhlmann, E., Himmler, S., Giebelhaus, H., & Wasserscheid, P. (2007) · Green Chem. · doi:10.1039/b611974c · Cited by 150 · see citing works
Kuhlmann, E., Himmler, S., Giebelhaus, H., & Wasserscheid, P. (2007) · ChemInform · doi:10.1002/chin.200730193 · Cited by 118 · see citing works
Allylimidazolium Halides as Novel Room Temperature Ionic Liquids
Mizumo, T., Marwanta, E., Matsumi, N., & Ohno, H. (2004) · Chemistry Letters · doi:10.1246/cl.2004.1360 · Cited by 92 · see citing works
Self-citationHimmler, S., Hörmann, S., van Hal, R., Schulz, P. S., & Wasserscheid, P. (2006) · Green Chemistry · doi:10.1039/b601583b · Cited by 77 · see citing works
SEC–MALLS analysis of cellulose using LiCl/1,3-dimethyl-2-imidazolidinone as an eluent
Yanagisawa, M., Shibata, I., & Isogai, A. (2004) · Cellulose · doi:10.1023/b:cell.0000025388.92043.ec · Cited by 55 · see citing works
Gopal, D. V., & Subrahmanyam, M. (2001) · Green Chemistry · doi:10.1039/b106183f · Cited by 14 · see citing works
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Sorted by citations
Ionic-liquid materials for the electrochemical challenges of the future
Armand, M. B., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009) · Nature Materials · doi:10.1038/nmat2448 · Cited by 4,616 · see citing works
Self-citationIonic liquids and catalysis: Recent progress from knowledge to applications
Olivier‐Bourbigou, H., Magna, L., & Morvan, D. L. (2009) · Applied Catalysis A General · doi:10.1016/j.apcata.2009.10.008 · Cited by 1,639 · see citing works
Deconstruction of lignocellulosic biomass with ionic liquids
Brandt, A., Gräsvik, J., Hallett, J. P., & Welton, T. (2013) · Green Chemistry · doi:10.1039/c2gc36364j · Cited by 1,557 · see citing works
Ionic Liquids and Their Interaction with Cellulose
Pinkert, A., Marsh, K. N., Pang, S., & Staiger, M. P. (2009) · Chemical Reviews · doi:10.1021/cr9001947 · Cited by 1,508 · see citing works
Ionic liquid processing of cellulose
Wang, H., Gurau, G., & Rogers, R. D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs15311d · Cited by 1,369 · see citing works
Khalil, H. P. S. A., Davoudpour, Y., Islam, N., Mustapha, A., Sudesh, K., Dungani, R., & Jawaid, M. (2013) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2013.08.069 · Cited by 1,348 · see citing works
Recent advances in regenerated cellulose materials
Wang, S., Lu, A., & Zhang, L. (2015) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2015.07.003 · Cited by 1,036 · see citing works
Sun, N., Rahman, M., Qin, Y., Maxim, M. L., Rodríguez, H., & Rogers, R. D. (2009) · Green Chemistry · doi:10.1039/b822702k · Cited by 988 · see citing works
Importance of chemical pretreatment for bioconversion of lignocellulosic biomass
Behera, S., Arora, R., Nandhagopal, N., & Kumar, S. (2014) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.04.047 · Cited by 953 · see citing works
Lee, S. H., Doherty, T. V., Linhardt, R. J., & Dordick, J. S. (2008) · Biotechnology and Bioengineering · doi:10.1002/bit.22179 · Cited by 942 · see citing works
E factors, green chemistry and catalysis: an odyssey
Sheldon, R. A. (2008) · Chemical Communications · doi:10.1039/b803584a · Cited by 888 · see citing works
New Frontiers in Materials Science Opened by Ionic Liquids
Torimoto, T., Tsuda, T., Okazaki, K., & Kuwabata, S. (2009) · Advanced Materials · doi:10.1002/adma.200902184 · Cited by 869 · see citing works
High-throughput screening for ionic liquids dissolving (ligno-)cellulose
Zavrel, M., Bross, D., Funke, M., Büchs, J., & Spieß, A. C. (2009) · Bioresource Technology · doi:10.1016/j.biortech.2008.11.052 · Cited by 696 · see citing works
Solvatochromic parameters for solvents of interest in green chemistry
Jessop, P. G., Jessop, D. A., Fu, D., & Phan, L. (2012) · Green Chemistry · doi:10.1039/c2gc16670d · Cited by 590 · see citing works
Overview of biomass pretreatment for cellulosic ethanol production.
Zheng, Y., Pan, Z., & Zhang, R. (2009) · International journal of agricultural and biological engineering · doi:10.25165/ijabe.v2i3.168 · Cited by 587 · see citing works
Dissolution of lignocellulosic materials and its constituents using ionic liquids—A review
Mäki‐Arvela, P., Anugwom, I., Virtanen, P., Sjöholm, R. E., & Mikkola, J. (2010) · Industrial Crops and Products · doi:10.1016/j.indcrop.2010.04.005 · Cited by 581 · see citing works
Preparation of cellulose-based hydrogel: a review
Zainal, S. H., Mohd, N. H., Suhaili, N., Anuar, F. H., Lazim, А. M., & Othaman, R. (2020) · Journal of Materials Research and Technology · doi:10.1016/j.jmrt.2020.12.012 · Cited by 579 · see citing works
Ionic liquids for energy, materials, and medicine
Śmiglak, M., Pringle, J. M., Lu, X., Han, L., Zhang, S., Gao, H., MacFarlane, D. R., & Rogers, R. D. (2014) · Chemical Communications · doi:10.1039/c4cc02021a · Cited by 510 · see citing works
Regenerating cellulose from ionic liquids for an accelerated enzymatic hydrolysis
Zhao, H., Jones, C. L., Baker, G. A., Xia, S., Olubajo, O., & Person, V. N. (2009) · Journal of Biotechnology · doi:10.1016/j.jbiotec.2008.08.009 · Cited by 492 · see citing works
Solubility of Carbohydrates in Ionic Liquids
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2010) · Energy & Fuels · doi:10.1021/ef901215m · Cited by 490 · see citing works
Ionic liquid-based green processes for energy production
Zhang, S., Sun, J., Zhang, X., Xin, J., Miao, Q., & Wang, J. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60409h · Cited by 473 · see citing works
Designing enzyme-compatible ionic liquids that can dissolve carbohydrates
Zhao, H., Baker, G. A., Song, Z., Olubajo, O., Crittle, T. D., & Peters, D. (2008) · Green Chemistry · doi:10.1039/b801489b · Cited by 467 · see citing works
Recent advances of enzymatic reactions in ionic liquids
Moniruzzaman, M., Nakashima, K., Kamiya, N., & Goto, M. (2009) · Biochemical Engineering Journal · doi:10.1016/j.bej.2009.10.002 · Cited by 450 · see citing works
Xu, A., Wang, J., & Wang, H. (2010) · Green Chem. · doi:10.1039/b916882f · Cited by 439 · see citing works
Advances on biomass pretreatment using ionic liquids: An overview
Tadesse, H., & Luque, R. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00667j · Cited by 434 · see citing works
Işık, M., Sardón, H., & Mecerreyes, D. (2014) · International Journal of Molecular Sciences · doi:10.3390/ijms150711922 · Cited by 431 · see citing works
Tan, S. S. Y., MacFarlane, D. R., Upfal, J., Edye, L. A., Doherty, W. O. S., Patti, A. F., Pringle, J. M., & Scott, J. L. (2009) · Green Chemistry · doi:10.1039/b815310h · Cited by 429 · see citing works
Sun, N., Rodríguez, H., Rahman, M., & Rogers, R. D. (2010) · Chemical Communications · doi:10.1039/c0cc03990j · Cited by 417 · see citing works
Zhang, J., Wu, J. L., Yu, J., Zhang, X., He, J., & Zhang, J. (2017) · Materials Chemistry Frontiers · doi:10.1039/c6qm00348f · Cited by 416 · see citing works
Green Solvents in Carbohydrate Chemistry: From Raw Materials to Fine Chemicals
Farrán, M. Á., Cai, C., Sandoval, M., Xu, Y., Liu, J., Hernáiz, M. J., & Linhardt, R. J. (2015) · Chemical Reviews · doi:10.1021/cr500719h · Cited by 392 · see citing works
Room temperature ionic liquids as emerging solvents for the pretreatment of lignocellulosic biomass
Mora‐Pale, M., Meli, L., Doherty, T. V., Linhardt, R. J., & Dordick, J. S. (2011) · Biotechnology and Bioengineering · doi:10.1002/bit.23108 · Cited by 384 · see citing works
Commercializing lignocellulosic bioethanol: technology bottlenecks and possible remedies
Banerjee, S., Mudliar, S., Sen, R., Giri, B., Satpute, D., Chakrabarti, T., & Pandey, R. A. (2010) · Biofuels, Bioproducts and Biorefining · doi:10.1002/bbb.188 · Cited by 377 · see citing works
Ionic liquid/water mixtures: from hostility to conciliation
Kohno, Y., & Ohno, H. (2012) · Chemical Communications · doi:10.1039/c2cc31638b · Cited by 366 · see citing works
Self-citationIonic Liquids — Promising but Challenging Solvents for Homogeneous Derivatization of Cellulose
Gericke, M., Fardim, P., & Heinze, T. J. (2012) · Molecules · doi:10.3390/molecules17067458 · Cited by 360 · see citing works
Competing forces during cellulose dissolution: From solvents to mechanisms
Medronho, B., & Lindman, B. (2014) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2013.12.001 · Cited by 356 · see citing works
Understanding the Interactions of Cellulose with Ionic Liquids: A Molecular Dynamics Study
Liu, H., Sale, K. L., Holmes, B. M., Simmons, B. A., & Singh, S. (2010) · The Journal of Physical Chemistry B · doi:10.1021/jp9117437 · Cited by 351 · see citing works
Elgharbawy, A. A. M., Alam, M. Z., Moniruzzaman, M., & Goto, M. (2016) · Biochemical Engineering Journal · doi:10.1016/j.bej.2016.01.021 · Cited by 345 · see citing works
The effect of the ionic liquid anion in the pretreatment of pine wood chips
Brandt, A., Hallett, J. P., Leak, D. J., Murphy, R. J., & Welton, T. (2010) · Green Chemistry · doi:10.1039/b918787a · Cited by 333 · see citing works
Task Specific Ionic Liquids for Cellulose Technology
Ohno, H., & Fukaya, Y. (2008) · Chemistry Letters · doi:10.1246/cl.2009.2 · Cited by 331 · see citing works
Self-citationInstantaneous dissolution of cellulose in organic electrolyte solutions
Rinaldi, R. (2010) · Chemical Communications · doi:10.1039/c0cc02421j · Cited by 330 · see citing works
Biodegradable transparent substrates for flexible organic-light-emitting diodes
Zhu, H., Xiao, Z., Liu, D., Li, Y., Weadock, N. J., Fang, Z., Huang, J., & Hu, L. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40492g · Cited by 324 · see citing works
Cao, Y., Wu, J. L., Zhang, J., Li, H., Zhang, Y., & He, J. (2008) · Chemical Engineering Journal · doi:10.1016/j.cej.2008.11.011 · Cited by 324 · see citing works
Thermophysical Characterization of Ionic Liquids Able To Dissolve Biomass
Freire, M. G., Teles, A. R. R., Rocha, M. A. A., Schröder, B., Neves, C. M. S. S., Carvalho, P. J., Evtuguin, D. V., Santos, L. M. N. B. F., & Coutinho, J. A. P. (2011) · Journal of Chemical & Engineering Data · doi:10.1021/je200790q · Cited by 323 · see citing works
Araque, J. C., Hettige, J. J., & Margulis, C. J. (2015) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.5b05506 · Cited by 320 · see citing works
Ionic liquid pretreatment of cellulosic biomass: Enzymatic hydrolysis and ionic liquid recycle
Shill, K., Padmanabhan, S., Xin, Q., Prausnitz, J. M., Clark, D. S., & Blanch, H. W. (2010) · Biotechnology and Bioengineering · doi:10.1002/bit.23014 · Cited by 315 · see citing works
Efficient biomass pretreatment using ionic liquids derived from lignin and hemicellulose
Socha, A. M., Parthasarathi, R., Shi, J., Pattathil, S., Whyte, D., Bergeron, M., George, A., Tran, K. L. T., Stavila, V., Venkatachalam, S., et al. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1405685111 · Cited by 308 · see citing works
Sen, S., Martin, J. D., & Argyropoulos, D. S. (2013) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc400085a · Cited by 298 · see citing works
Ionic liquids as a potential tool for drug delivery systems
Mustahil, N. A., Moniruzzaman, M., Baharuddin, S. H., & Goto, M. (2016) · MedChemComm · doi:10.1039/c6md00358c · Cited by 298 · see citing works
Role of Solvent Parameters in the Regeneration of Cellulose from Ionic Liquid Solutions
Hauru, L. K. J., Hummel, M., King, A. W. T., Kilpeläinen, I., & Sixta, H. (2012) · Biomacromolecules · doi:10.1021/bm300912y · Cited by 288 · see citing works
Ionic liquids and deep eutectic solvents for lignocellulosic biomass fractionation
van Osch, D. J. G. P., Kollau, L. J. B. M., van den Bruinhorst, A., Asikainen, S., Rocha, M. A. A., & Kroon, M. C. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp07499e · Cited by 287 · see citing works
IR Study on Cellulose with the Varied Moisture Contents: Insight into the Supramolecular Structure
Cichosz, S., & Masek, A. (2020) · Materials · doi:10.3390/ma13204573 · Cited by 259 · see citing works
Badgujar, K. C., & Bhanage, B. M. (2014) · Bioresource Technology · doi:10.1016/j.biortech.2014.09.138 · Cited by 254 · see citing works
Farooq, A., Patoary, M. K., Zhang, M., Mussana, H., Li, M., Naeem, M. A., Mushtaq, M., Farooq, A., & Liu, L. (2020) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2020.03.163 · Cited by 252 · see citing works
Cellulose Solvents – Remarkable History, Bright Future
Liebert, T. (2010) · ACS Symposium Series · doi:10.1021/bk-2010-1033.ch001 · Cited by 250 · see citing works
Lindman, B., Medronho, B., Alves, L., Costa, C., Edlund, H., & Norgren, M. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp02409f · Cited by 249 · see citing works
Cation does matter: how cationic structure affects the dissolution of cellulose in ionic liquids
Lu, B., Xu, A., & Wang, J. (2013) · Green Chemistry · doi:10.1039/c3gc41733f · Cited by 249 · see citing works
Extended scale for the hydrogen-bond basicity of ionic liquids
Cláudio, A. F. M., Swift, L., Hallett, J. P., Welton, T., Coutinho, J. A. P., & Freire, M. G. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp55285c · Cited by 248 · see citing works
Qiu, Z., Aita, G. M., & Walker, M. S. (2012) · Bioresource Technology · doi:10.1016/j.biortech.2012.04.070 · Cited by 246 · see citing works
Ionic liquids for biofuel production: Opportunities and challenges
Liu, C.-Z., Wang, F., Stiles, A. R., & Guo, C. (2012) · Applied Energy · doi:10.1016/j.apenergy.2011.11.031 · Cited by 236 · see citing works
Morais, E. S., Lopes, A. M. D. C., Freire, M. G., Freire, C. S. R., Coutinho, J. A. P., & Silvestre, A. J. D. (2020) · Molecules · doi:10.3390/molecules25163652 · Cited by 239 · see citing works
Ionic liquid-assisted transdermal delivery of sparingly soluble drugs
Moniruzzaman, M., Tahara, Y., Tamura, M., Kamiya, N., & Goto, M. (2010) · Chemical Communications · doi:10.1039/b907462g · Cited by 235 · see citing works
Distillable Acid–Base Conjugate Ionic Liquids for Cellulose Dissolution and Processing
King, A. W. T., Asikkala, J., Mutikainen, I., Järvi, P., & Kilpeläinen, I. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100274 · Cited by 234 · see citing works
Ionic liquid tolerant hyperthermophilic cellulases for biomass pretreatment and hydrolysis
Datta, S., Holmes, B. M., Park, J. I., Chen, Z., Dibble, D., Hadi, M. Z., Blanch, H. W., Simmons, B. A., & Sapra, R. (2010) · Green Chemistry · doi:10.1039/b916564a · Cited by 229 · see citing works
Progress on the pre-treatment of lignocellulosic biomass employing ionic liquids
Halder, P. K., Kundu, S. K., Patel, S., Setiawan, A., Atkin, R., Parthasarthy, R., Paz‐Ferreiro, J., Surapaneni, A., & Shah, K. V. (2019) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2019.01.052 · Cited by 230 · see citing works
Comprehensive Refractive Index Property for Room-Temperature Ionic Liquids
Seki, S., Tsuzuki, S., Hayamizu, K., Umebayashi, Y., Serizawa, N., Takei, K., & Miyashiro, H. (2012) · Journal of Chemical & Engineering Data · doi:10.1021/je201289w · Cited by 218 · see citing works
Lan, W., Liu, C., & Sun, R. (2011) · Journal of Agricultural and Food Chemistry · doi:10.1021/jf201508g · Cited by 216 · see citing works
Xu, A., Zhang, Y., Zhao, Y., & Wang, J. (2012) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2012.09.028 · Cited by 211 · see citing works
Hydrolysis of cellulose by the heteropoly acid H3PW12O40
Tian, J., Wang, J., Zhao, S., Jiang, C., Zhang, X., & Wang, X. (2010) · Cellulose · doi:10.1007/s10570-009-9391-0 · Cited by 210 · see citing works
Enzymatic in situ saccharification of cellulose in aqueous-ionic liquid media
Kamiya, N., Matsushita, Y., Hanaki, M., Nakashima, K., Narita, M., Goto, M., & Takahashi, H. (2008) · Biotechnology Letters · doi:10.1007/s10529-008-9638-0 · Cited by 207 · see citing works
Moniruzzaman, M., Kamiya, N., & Goto, M. (2010) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2010.08.035 · Cited by 203 · see citing works
Rinaldi, R., Meine, N., vom Stein, J., Palkovits, R., & Schüth, F. (2010) · ChemSusChem · doi:10.1002/cssc.200900281 · Cited by 201 · see citing works
Liebert, T. F., & Heinze, T. J. (2008) · BioResources · doi:10.15376/biores.3.2.576-601 · Cited by 198 · see citing works
Remsing, R. C., Hernandez, G., Swatloski, R. P., Massefski, W. W., Rogers, R. D., & Moyna, G. (2008) · The Journal of Physical Chemistry B · doi:10.1021/jp8042895 · Cited by 193 · see citing works
Ionic liquids in the biorefinery: a critical assessment of their potential
Stark, A. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00246a · Cited by 193 · see citing works
Polymers in Ionic Liquids: Dawn of Neoteric Solvents and Innovative Materials
Ueki, T., & Watanabe, M. (2011) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20110225 · Cited by 184 · see citing works
Extreme Light Management in Mesoporous Wood Cellulose Paper for Optoelectronics
Zhu, H., Fang, Z., Wang, Z., Dai, J., Yao, Y., Shen, F., Preston, C., Wu, W., Peng, P., Jang, N., et al. (2015) · ACS Nano · doi:10.1021/acsnano.5b06781 · Cited by 185 · see citing works
Biomass deconstruction to sugars
Blanch, H. W., Simmons, B. A., & Klein‐Marcuschamer, D. (2011) · Biotechnology Journal · doi:10.1002/biot.201000180 · Cited by 182 · see citing works
15th anniversary of polymerised ionic liquids
Nishimura, N., & Ohno, H. (2014) · Polymer · doi:10.1016/j.polymer.2014.02.042 · Cited by 181 · see citing works
Self-citationXia, S., Baker, G. A., Li, H., Ravula, S., & Zhao, H. (2013) · RSC Advances · doi:10.1039/c3ra46149a · Cited by 177 · see citing works
Biocatalysis and Biomass Conversion in Alternative Reaction Media
Sheldon, R. A. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201601940 · Cited by 177 · see citing works
Dissolution of cellulose in ionic liquids and their mixed cosolvents: A review
Verma, C., Mishra, A., Chauhan, S., Verma, P., Srivastava, V., Quraishi, M. A., & Ebenso, E. E. (2019) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2019.100162 · Cited by 178 · see citing works
Ionic liquids: not always innocent solvents for cellulose
Clough, M. T., Geyer, K., Hunt, P. A., Son, S., Vagt, U., & Welton, T. (2014) · Green Chemistry · doi:10.1039/c4gc01955e · Cited by 177 · see citing works
Abe, M., Fukaya, Y., & Ohno, H. (2012) · Chemical Communications · doi:10.1039/c2cc16203b · Cited by 176 · see citing works
Self-citationChen, Q., Xu, A., Li, Z., Wang, J., & Zhang, S. (2011) · Green Chemistry · doi:10.1039/c1gc15703e · Cited by 174 · see citing works
Room Temperature Ionic Liquids Meet Biomolecules: A Microscopic View of Structure and Dynamics
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Bhat, A. H., Khan, I., Usmani, M. A., Umapathi, R., & Al‐Kindy, S. M. Z. (2018) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2018.12.190 · Cited by 170 · see citing works
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Lan, W., Liu, C., Yue, F., Sun, R., & Kennedy, J. F. (2011) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2011.05.013 · Cited by 167 · see citing works
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Abe, M., Fukaya, Y., & Ohno, H. (2010) · Green Chemistry · doi:10.1039/c003976d · Cited by 166 · see citing works
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Szabó, L., Milotskyi, R., Sharma, G., & Takahashi, K. (2023) · Green Chemistry · doi:10.1039/d2gc04730f · Cited by 162 · see citing works
Mahmood, H., Moniruzzaman, M., Yusup, S. B., & Welton, T. (2017) · Green Chemistry · doi:10.1039/c7gc00318h · Cited by 158 · see citing works
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Desai, R. K., Streefland, M., Wijffels, R. H., & Eppink, M. H. M. (2015) · Green Chemistry · doi:10.1039/c5gc01301a · Cited by 153 · see citing works
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Froschauer, C., Hummel, M., Iakovlev, M., Roselli, A., Schottenberger, H., & Sixta, H. (2013) · Biomacromolecules · doi:10.1021/bm400106h · Cited by 146 · see citing works
- Authors
- Fukaya, Y., Hayashi, K., Wada, M., & Ohno, H.
- Affiliations
- Tokyo University of Agriculture and Technology (JP)
- The University of Tokyo (JP)
- Corresponding author
- Ohno, Hiroyuki
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 10
- Issue
- 1
- Pages
- 44-46
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W1980836177
- Cited by
- 775
- References
- 23
- Citations by year
- 2026: 12 · 2025: 14 · 2024: 20 · 2023: 15 · 2022: 30 · 2021: 24 · 2020: 33 · 2019: 60 · 2018: 42 · 2017: 67 · 2016: 50 · 2015: 58 · 2014: 75 · 2013: 58 · 2012: 63
- FWCI
- 13.36
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Green Chemistry (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Keywords
- cellulose dissolution, room temperature ionic liquids, anion effects, dimethyl phosphate, cellulose solubilization, cellulose solutions
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