The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Modulation of Cellulose Nanocrystals Amphiphilic Properties to Stabilize Oil/Water Interface
Abstract
Neutral cellulose nanocrystals dispersed in water were shown in a previous work to stabilize oil/water interfaces and produce Pickering emulsions with outstanding stability, whereas sulfated nanocrystals obtained from cotton did not show interfacial properties. To develop a better understanding of the stabilization mechanism, amphiphilic properties of the nanocrystals were modulated by tuning the surface charge density to investigate emulsifying capability on two sources of cellulose: cotton linters (CCN) and bacterial cellulose (BCN). This charge adjustment made it possible to determine the conditions where a low surface charge density, below 0.03 e/nm(2), remains compatible with emulsification, as well as when assisted by charge screening regardless of the source. This study discusses this ability to stabilize oil-in-water emulsions for cellulose nanocrystals varying in crystalline allomorph, morphology, and hydrolysis processes related to the amphiphilic character of nonhydrophobized cellulose nanocrystal.
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Cites
Effect of microcrystallite preparation conditions on the formation of colloid crystals of cellulose
DONG, X. M., REVOL, J.-F., & GRAY, D. G. (1998) · Cellulose · doi:10.1023/a:1009260511939 · Cited by 1,032
Sugiyama, J., Vuong, R., & Chanzy, H. (1991) · Macromolecules · doi:10.1021/ma00014a033 · Cited by 791
Araki, J., Wada, M., Kuga, S., & Okano, T. (1998) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/s0927-7757(98)00404-x · Cited by 769
Cited by
Emulsions stabilized with solid nanoparticles: Pickering emulsions
Chevalier, Y., & Bolzinger, M.-A. (2013) · Colloids and Surfaces A: Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2013.02.054 · Cited by 1,765
Current characterization methods for cellulose nanomaterials
Foster, E. J., Moon, R. J., Agarwal, U. P., Bortner, M. J., Bras, J., Camarero-Espinosa, S., Chan, K. J., Clift, M. J. D., Cranston, E. D., Eichhorn, S. J., et al. (2018) · Chemical Society Reviews · doi:10.1039/c6cs00895j · Cited by 1,021
Klemm, D., Cranston, E. D., Fischer, D., Gama, M., Kedzior, S. A., Kralisch, D., Kramer, F., Kondo, T., Lindström, T., Nietzsche, S., et al. (2018) · Materials Today · doi:10.1016/j.mattod.2018.02.001 · Cited by 936
Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions
Kalashnikova, I., Bizot, H., Bertoncini, P., Cathala, B., & Capron, I. (2013) · Soft Matter · doi:10.1039/c2sm26472b · Cited by 622
Self-citationRecent advances in the application of cellulose nanocrystals
Grishkewich, N., Mohammed, N., Tang, J., & Tam, K. C. (2017) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2017.01.005 · Cited by 621
Metadata
- Authors
- Kalashnikova, I., Bizot, H., Cathala, B., & Capron, I.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-12-14
- Volume
- 13
- Issue
- 1
- Pages
- 267-275
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W2321524710
- Cited by
- 637
- References
- 3
- FWCI
- 6.05
- Type
- journal article
- Language
- en
- Open access
- closed
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