The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Cellulosic nanorods of various aspect ratios for oil in water Pickering emulsions
Abstract
Cellulosic colloidal nanorods of different origins were used in order to investigate the effect of various elongated shapes adsorbed at the oil–water interface for Pickering emulsion characteristics. Nanocrystals of length ranging from 185 nm to 4 μm were obtained from the hydrolysis of cellulose microfibrils of three different biological origins: cotton (CCN), bacterial cellulose (BCN) and Cladophora (ClaCN) leading to aspect ratios ranging from 13 to 160. These nanocrystals are irreversibly adsorbed at the oil–water interface and form ultrastable emulsions. Individual droplets of similar diameter were obtained under diluted conditions, illustrating both similar wetting properties and nanocrystal flexibility for the three different types of nanocrystals. However, it was shown that the aspect ratio directly influences the coverage ratio giving rise, on the one hand to a dense organisation (coverage >80%) with short nanocrystals and on the other hand to an interconnected network of low covered droplets (40%) when longer nanocrystals are used. An estimation is made showing that for the longer nanocrystals, 55% of the nanocrystals introduced are involved in the network of the material. The capillary force that promotes attractive interactions between nanocrystals was also addressed. These results lead to a better understanding of the adsorption process for rod-like particles of various aspect ratios for the elaboration of a controlled surface architecture, from a homogeneous monolayer to interconnected porous multilayered interfaces.
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Cites
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Cited by
Nanocellulose: From Fundamentals to Advanced Applications
Trache, D., Tarchoun, A. F., Derradji, M., Hamidon, T. S., Masruchin, N., Brosse, N., & Hussin, M. H. (2020) · Frontiers in Chemistry · doi:10.3389/fchem.2020.00392 · Cited by 1,309
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Benchmarking Cellulose Nanocrystals: From the Laboratory to Industrial Production
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Pickering stabilization of foams and emulsions with particles of biological origin
Lam, S., Velikov, K. P., & Velev, O. D. (2014) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2014.07.003 · Cited by 493
Metadata
- Authors
- Kalashnikova, I., Bizot, H., Bertoncini, P., Cathala, B., & Capron, I.
- Venue
- Soft Matter
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2013
- Volume
- 9
- Issue
- 3
- Pages
- 952-959
- ISSN
- 1744-683X (ISSN-L)
- 1744-6848
- OpenAlex
- W2156838050
- Cited by
- 622
- References
- 28
- FWCI
- 9.12
- Type
- journal article
- Language
- en
- Open access
- closed
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