The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Ultrastrong and High Gas-Barrier Nanocellulose/Clay-Layered Composites
Abstract
Nanocellulose/montmorillonite (MTM) composite films were prepared from 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-oxidized cellulose nanofibrils (TOCNs) with an aspect ratio of >200 dispersed in water with MTM nanoplatelets. The composite films were transparent and flexible and showed ultrahigh mechanical and oxygen barrier properties through the nanolayered structures, which were formed by compositing the anionic MTM nanoplatelet filler in anionic and highly crystalline TOCN matrix. A composite film with 5% MTM content had Young's modulus 18 GPa, tensile strength 509 MPa, work of fracture of 25.6 MJ m(-3), and oxygen permeability 0.006 mL μm m(-2) day(-1) kPa(-1) at 0% relative humidity, respectively, despite having a low density of 1.99 g cm(-3). As the MTM content in the TOCN/MTM composites was increased to 50%, light transmittance, tensile strength, and elongation at break decreased, while Young's modulus was almost unchanged and oxygen barrier property was further improved to 0.0008 mL μm m(-2) day(-1) kPa(-1).
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Cites
Tough, Bio-Inspired Hybrid Materials
Munch, E., Launey, M. E., Alsem, D. H., Saiz, E., Tomsia, A. P., & Ritchie, R. O. (2008) · Science · doi:10.1126/science.1164865 · Cited by 1,822
Saito, T., Nishiyama, Y., Putaux, J.-L., Vignon, M., & Isogai, A. (2006) · Biomacromolecules · doi:10.1021/bm060154s · Cited by 1,796
Self-citationTransparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation
Fukuzumi, H., Saito, T., Iwata, T., Kumamoto, Y., & Isogai, A. (2009) · Biomacromolecules · doi:10.1021/bm801065u · Cited by 1,271
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Cited by
Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications
Zhu, H., Luo, W., Ciesielski, P. N., Fang, Z., Zhu, J. Y., Henriksson, G., Himmel, M. E., & Hu, L. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00225 · Cited by 1,532
Moisture and Oxygen Barrier Properties of Cellulose Nanomaterial-Based Films
Wang, J., Gardner, D. J., Stark, N. M., Bousfield, D. W., Tajvidi, M., & Cai, Z. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b03523 · Cited by 675
Nanocellulose in Thin Films, Coatings, and Plies for Packaging Applications: A Review
Hubbe, M. A., Ferrer, A., Tyagi, P., Yin, Y., Salas, C., Pal, L., & Rojas, O. J. (2017) · BioResources · doi:10.15376/biores.12.1.2143-2233 · Cited by 508
Cellulose Nanoparticles as Modifiers for Rheology and Fluid Loss in Bentonite Water-based Fluids
Li, M.-C., Wu, Q., Song, K., Qing, Y., & Wu, Y. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b00498 · Cited by 373
Benítez, A. J., Torres-Rendon, J., Poutanen, M., & Walther, A. (2013) · Biomacromolecules · doi:10.1021/bm401451m · Cited by 287
Metadata
- Authors
- Wu, C.-N., Saito, T., Fujisawa, S., Fukuzumi, H., & Isogai, A.
- Venue
- Biomacromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-05-15
- Volume
- 13
- Issue
- 6
- Pages
- 1927-1932
- ISSN
- 1525-7797 (ISSN-L)
- 1526-4602
- OpenAlex
- W2067653939
- Cited by
- 303
- References
- 3
- FWCI
- 9.86
- Type
- journal article
- Language
- en
- Open access
- closed
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