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Supramolecular Coordination Chemistry and Functional Microporous Molecular Materials
Abstract
An enormous number and variety of discrete, isolable, supramolecular-coordination-chemistry-based assemblies featuring well-defined nanoscale cavities have been designed, synthesized, and characterized over the past decade. A small number of these have subsequently been used as building blocks for microporous materials and now comprise an important component of an emerging chemistry of microporous molecular materials. The extant materials typically have displayed large void volumes, high internal surface areas, and the ability to withstand the systematic removal of solvent. These and other properties (chemical tailorability, alignment of cavities to form extended channels, good processability, etc.) suggest a number of potentially very exciting applications involving selective molecular transport, sensing, or chemical transformation with many of these now supported by proof-of-concept experiments.
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Citations
Cites
Isolation of New Ribozymes from a Large Pool of Random Sequences
Bartel, D. P., & Szostak, J. W. (1993) · Science · doi:10.1126/science.7690155 · Cited by 900
Cited by
Design of New Materials for Methane Storage
Düren, T., Sarkisov, L., Yaghi, O. M., & Snurr, R. Q. (2004) · Langmuir · doi:10.1021/la0355500 · Cited by 731
Prospects for nanoporous metal‐organic materials in advanced separations processes
Snurr, R. Q., Hupp, J. T., & Nguyen, S. T. (2004) · AIChE Journal · doi:10.1002/aic.10101 · Cited by 262
Self-citationWater‐Insoluble Ag–U–Organic Assemblies with Photocatalytic Activity
Yu, Z., Liao, Z., Jiang, Y., Li, G., & Chen, J. (2005) · Chemistry – A European Journal · doi:10.1002/chem.200401189 · Cited by 254
Metadata
- Authors
- Dinolfo, P. H., & Hupp, J. T.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-09-05
- Volume
- 13
- Issue
- 10
- Pages
- 3113-3125
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2168637788
- Cited by
- 325
- References
- 1
- FWCI
- 20.06
- Type
- journal article
- Language
- en
- Open access
- closed
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