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A Detailed Study of Thermal, Hydrothermal, and Mechanical Stabilities of a Wide Range of Surfactant Assembled Mesoporous Silicas

Cassiers, K., Linssen, T., Mathieu, M., Benjelloun, M., Schrijnemakers, K., Van Der Voort, P., Cool, P., Vansant, E. F.·2002·Chemistry of Materials

Abstract

The thermal, hydrothermal, and mechanical stabilities of a wide range of ordered mesoporous materials, in particular, the molecular sieves MCM-41, MCM-48, HMS, FSM-16, KIT-1, PCH, and SBA-15, have been studied in detail using X-ray diffraction (XRD) and nitrogen sorption. The thermal stability was found to be strongly related to the wall thickness and the silica precursor used during synthesis, and the following stability trend was observed: MCM-41 (fumed silica), MCM-48 (fumed silica), KIT-1 (colloid silica) > SBA-15 (TEOS) > FSM-16 (layered silicate), PCH (layered silicate) > MCM-41 (TEOS), MCM-48 (TEOS), HMS (TEOS). The hydrothermal stability is influenced by the wall thickness and the polymerization degree and decreases according to the following trend: KIT-1 > SBA-15 > MCM-48 (fumed silica and TEOS), PCH > FSM-16, MCM-41 (fumed silica and TEOS), HMS. The mechanical stability is little influenced by the nature of the mesoporous molecular sieves. All materials collapsed at a maximum pelletizing pressure of 450 MPa.

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Authors
Cassiers, K., Linssen, T., Mathieu, M., Benjelloun, M., Schrijnemakers, K., Van Der Voort, P., Cool, P., & Vansant, E. F.
Venue
Chemistry of Materials
Published
2002-04-09
Volume
14
Issue
5
Pages
2317-2324
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W1986733551
Cited by
355
References
2
FWCI
10.76
Type
journal article
Language
en
Open access
closed

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