Microemulsion-assisted synthesis of tunable superparamagnetic composites
Abstract
Tunable superparamagnetic materials have been obtained by the thermal annealing of iron oxide/silica composites synthesized using microemulsions with a high content of the iron oxide precursor. The crystallochemical characteristics of the powders obtained after controlled hydrolysis within the reverse micelle nanocavities and their thermal evolution up to the formation of the γ-Fe 2 O 3 crystalline phase were studied. The thermally annealed composites clearly exhibited superparamagnetic behavior with the value of the saturation magnetization easily tuned by changing the iron oxide content and the annealing temperature. Information on the influence of particle size and interparticle interactions on the magnetic properties of the composites was inferred from zero field and field cooling measurements and also from the decay of the reduced remanence with temperature. It was observed that the blocking temperature increased with content and particle size of γ-Fe 2 O 3 . We have also determined a strong dependence of the effective anisotropy with the particle size associated with the existence of surface anisotropy.
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Maintenance of micelle structure at high reaction temperature or thermal annealing of synthesized iron oxide are ways to increase the crystallinity of particles prepared by microemulsion.
“Maintenance of micelle structure at high reaction temperature [41] or thermal annealing of synthesized iron oxide [42] are ways to increase the crystallinity of the particles prepared by this method.”
From Iron oxide nanoparticles: Diagnostic, therapeutic and theranostic applications (2019) · cites this paper as [42]
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- Authors
- Tartaj, P., & Serna, C. J.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Corresponding author
- Tartaj, Pedro
- ORCID
- Tartaj, Pedro
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-09-19
- Volume
- 14
- Issue
- 10
- Pages
- 4396-4402
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2061192039
- Cited by
- 110
- References
- 30
- Citations by year
- 2026: 1 · 2025: 4 · 2024: 1 · 2023: 3 · 2022: 2 · 2021: 8 · 2019: 5 · 2018: 1 · 2017: 3 · 2016: 3 · 2015: 5 · 2014: 6 · 2013: 4 · 2012: 6
- FWCI
- 3.74
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry of Materials (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Magnetic Properties and Synthesis of Ferrites
- Physical Sciences › Engineering › Biomedical Engineering › Characterization and Applications of Magnetic Nanoparticles
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Geomagnetism and Paleomagnetism Studies
- Keywords
- superparamagnetism, microemulsion synthesis, reverse micelles, annealing, maghemite, saturation magnetization, blocking temperature, magnetic anisotropy, surface anisotropy, particle size effects, interparticle interactions, field cooling
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