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Cited by 443

The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.

Characterization of the Structural, Optical, and Dielectric Properties of Oxynitride Perovskites AMO2N (A = Ba, Sr, Ca; M = Ta, Nb)

Kim, Young-Il, Woodward, Patrick M., Baba-Kishi, Karim Z., Tai, Cheuk W.·2004·Chemistry of Materials
DOI 10.1021/cm034756j
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Abstract

The syntheses, crystal structures, electrical properties, and optical absorbance spectra of six perovskite oxynitrides, AMO 2 N (A = Ba, Sr, Ca; M = Ta, Nb) have been investigated. The average crystal structure of BaTaO 2 N is a cubic perovskite, with a Ta−O/N distance of 2.056 Å. SrTaO 2 N and CaTaO 2 N are distorted by octahedral tilting, showing noticeably smaller Ta−O/N distances of approximately 2.02 Å. Electron diffraction studies of BaTaO 2 N are consistent with the simple cubic perovskite crystal structure determined using X-ray powder diffraction methods. Each of the niobium oxynitrides is isostructural with its tantalum analogue, though the Nb−O/N distances are observed to be slightly longer. The optical band gaps are estimated from diffuse reflectance spectra as follows: BaTaO 2 N, 1.8 eV; SrTaO 2 N, 2.1 eV; CaTaO 2 N, 2.4 eV; BaNbO 2 N, 1.8 eV; SrNbO 2 N, 1.9 eV; CaNbO 2 N, 2.1 eV. Impedance spectroscopy was carried out on sintered pellets of the ATaO 2 N and BaNbO 2 N to investigate the dielectric and electrical transport properties. The BaNbO 2 N sample shows metallic-type conductivity apparently from a slight reduction that occurs during sintering. In contrast, the tantalum compounds are semiconductors/insulators with conductivities of ∼10 - 5 S/cm (A = Ba, Sr) and ∼10 - 8 S/cm (A = Ca). Interpretation of the impedance data for BaTaO 2 N and SrTaO 2 N reveals that these two compounds have unexpectedly high bulk dielectric constants, κ ≈ 4900 and 2900, respectively, at room temperature. The dielectric constants of both compounds are frequency dependent and show a relatively weak linear dependence upon temperature with no sign of a phase transition over the temperature range 300−180 K.

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Metadata

Authors
Kim, Y.-I., Woodward, P. M., Baba-Kishi, K. Z., & Tai, C. W.
Venue
Chemistry of Materials
Publisher
American Chemical Society (ACS)
Published
2004-03-09
Volume
16
Issue
7
Pages
1267-1276
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
DOI
10.1021/cm034756j
OpenAlex
W2067448380
Cited by
443
References
23
FWCI
5.30
Type
journal article
Language
en
Open access
closed

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